Statistical Thermodynamics of Liquid Alkali Alloys
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概要
- 論文の詳細を見る
A statistical mechanical calculation of liquid alkali alloys (Na -Rb, Na-Cs,K-Rb, K-Cs and Rb-Cs) is performed by using the generalized van der Waalstheory associated with a uniform background potential of F-"'-dependence(F: volume). Excess thermodynamic functions, structure factors and concentra-tion fluctuations are calculated and discussed. Negatively large excess volumeand small excess entropy characteristic of liquid alkali alloys are reasonablyexplained. It is found that a marked increase in the concentration fluctuation ofNa -Cs alloys is primarily determined by the difference in sizes of constituent tons.
- 社団法人日本物理学会の論文
- 1983-06-15
著者
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OHTOMO Norio
Faculty of Engineering, Hokkaido University
-
Tanaka Yukio
Faculty Of Engineering Hokkaido University
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Ohtomo Norio
Faculty Of Engineering Hokkaido University
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ARAKAWA Kiyoshi
Research Institute of Applied Electricity,Hokkaido University
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Arakawa Kiyoshi
Research Institute Of Applied Electricity Hokkaido University
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