Cyanation of 1-halocycloalkenes catalyzed by tetracyanocobaltate(I). Convenient synthesis of 1-cyanocycloalkenes.
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概要
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1-Cyanocycloalkenes (1-cyanocyclopentene, -hexene, -heptene, and -octene) were readily synthesized by catalytic cyanation of the corresponding 1-halocycloalkenes with tetracyanocobaltate(I). Reactivities of methyl-substituted 1-chlorocyclohexenes were lower than that of 1-chlorocyclohexene, and 1-chloro-2-methylcyclohexene scarecely reacted. Hydrogenation and isomerization of 1-cyanocycloalkenes were observed only with 1-cyanocycloheptene and 1-cyano-6-methylcyclohexene, respectively.
- 公益社団法人 日本化学会の論文
著者
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Funabiki Takuzo
Department Of Hydrocarbon Chemistry And Division Of Molecular Engineering Faculty Of Engineering Kyo
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Yoshida Satohiro
Department Of Hydrocarbon Chemistry And Division Of Molecular Engineering Faculty Of Engineering Kyo
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Sato Yoshihiro
Department of Applied Biological Science, Tokyo University of Science
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Sato Yoshihiro
Department of Hydrocarbon Chemistry, Faculty of Engineering, Kyoto University
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Kishi Hirohito
Department of Hydrocarbon Chemistry, Faculty of Engineering, Kyoto University
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