Chemistry of 1,2-thiaphosphole 2-sulfides. I. Cycloaddition reactions of 1,2-thiaphosphole 2-sulfides with some dienophiles.
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概要
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2,9-Dithia-1-phosphabicyclo[4.3.0]nona-3,7-diene 1-sulfides have been prepared by the reaction of α,β unsaturated ketones with P<SUB>4</SUB>S<SUB>10</SUB> in the presence of NEt<SUB>3</SUB>. 1,2-Thiaphosphole 2-sulfides generated by the thermolysis of the phosphabicyclo compounds underwent cycloaddition reactions with acrylonitrile, styrene, butyl vinyl ether and norbornene to give the [4+2]cycloadducts, respectively.
- 公益社団法人 日本化学会の論文
著者
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Kametani Shunichi
Department Of Life Sciences (chemistry) Graduate School Of Arts And Sciences The University Of Tokyo
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Motoki Shinichi
Department Of Chemistry Faculty Of Science Science University Of Tokyo
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Tanaka Hideyuki
Department Of Agricultural Chemistry Faculty Of Agriculture Utsunomiya University
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Saito Takao
Department Of Biochemistry And Surgery Oita Medical School
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