Studies of spin-labeled sodium dodecyl sulfate. II Effect of sodium chloride on ESR line width.
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概要
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The ESR spectra of spin-labeled sodium dodecyl sulfate were examined by changing the concentration, temperature, and ionic strength. The broadening of ESR lines due to a monomer surfactant could be explained in terms of an electron-spin exchange and a monomer-micelle exchange. The spin-exchange rate increased with increasing temperature and decreased with increasing ionic strength, i.e., the spin-exchange frequency was closely related to the viscosity of the medium. On the basis of an analysis of the line width above the critical micelle concentration, it was found that the aggregation number of the micelle of this compound and the monomer-micelle exchange frequency were dependent on the ionic strength.
- 公益社団法人 日本化学会の論文
著者
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Yamaguchi Takeo
Department Of Chemical System Engineering The University Of Tokyo
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Kimoto Eiji
Department Of Chemistry Faculty Of Science Fukuoka University
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Yamauchi Akira
Department Of Biochemistry Kawasaki Medical Schoo
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Kimizuka Hideo
Department of Chemistry Faculty of Science Kyushu University
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