A behavior of Donnan salt within membrane.
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概要
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In an amphoteric ion exchange membrane-electrolyte system, three independent experiments were carried out, that is, the membrane potential, membrane conductance and concentration of ions within membrane were measured, respectively. The electrolytes adopted in the systems were NaCl, CaCl<SUB>2</SUB>, LaCl<SUB>3</SUB>. From the analysis of the results, the specific conductance attributed to Donnan salt within membrane was separated. As a result, it was pointed out that the dynamic state of Donnan salt is obviously different from that of salt in aqueous solution. Furthermore, the comparison between the ions constituting Donnan salt and the counterions which interact with the ion-exchange sites suggested us the existance of two different dynamic states on the ions within membrane.
- 公益社団法人 日本化学会の論文
著者
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Yamauchi Akira
Department Of Biochemistry Kawasaki Medical Schoo
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Kimizuka Hideo
Department of Chemistry Faculty of Science Kyushu University
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Date Masashi
Department of Chemistry, Faculty of Science, Kyushu University 33
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Yamamoto Yukiko
Department of Chemistry, Faculty of Science, Kyushu University 33
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Hirata Yutaka
Department of Chemistry, Faculty of Science, Kyushu University 33
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