High-pressure aminolysis of lactones to hydroxy amides.
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概要
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The preparation of hydroxy amides from a wide variety of lactones and amines has been achieved at 9 kbar and 30 or 65 °C. The yields of hydroxy amides were moderate to excellent. Some limitations were encountered in the reaction of 6-hexanolide; for example, diethylamine gave only a 15% yield of the corresponding amide at 8 kbar and 60 °C. 4-Pentanolide did react with extremely unreactive amines such as 4-nitroaniline and diphenylamine, and the product was a mixture of the hydroxy amide and 3-aminobutyric acid.
- 公益社団法人 日本化学会の論文
著者
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Matsumoto Kiyoshi
Department Of Applied Chemistry Faculty Of Engineering Kanagawa University
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OTANI Shinichi
Department of General Thoracic Surgery, Jichi Medical University and Saitama Medical Center
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Okamoto Tadashi
Institute For Chemical Research Kyoto University
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Hashimoto Shiro
Department of Chemistry, College of Liberal Arts and Sciences, Kyoto University
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Uchida Takane
Faculty of Education, Fukui University
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Otani Shinichi
Department of Chemistry, College of Liberal Arts and Sciences, Kyoto University
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