Synthesis of both the enantiomers of phoracantholide I, a defensive secretion of the eucarypt longicorn (Phoracantha synonyma), employing microbial asymmetric reduction with immobilized baker's yeast.
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概要
- 論文の詳細を見る
Highly optically pure (<I>R</I>)- and (<I>S</I>)-phoracantholide I were synthesized in relatively short steps starting from diethyl 3-oxoglutarate by means of a microbial asymmetric reduction of the intermediate keto acid with immobilized baker's yeast entrapped in gels of κ-carrageenan.
- 公益社団法人 日本化学会の論文
著者
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Naoshima Yoshinobu
Department Of Agricultural Chemistry University Of Osaka Prefecture
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Nakamura Akihiro
Department Of Applied Chemistry And Biotechnology Faculty Of Engineering Yamanashi University
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Nishiyama Tadashi
Department of Biological Chemistry, Faculty of Science, Okayama University of Science
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Hasegawa Hidenobu
Midori Kagaku Co., Ltd.
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