Synthesis of Racemates and (+)-Enantiomers of f-γCaprolactone, γ-Dodecanolactone and δ-Hexadecanolactone, Lactonic Sex Pheromones of the Dermestid Beetle, Rove Beetle and Oriental Hornet
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概要
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A simple method based on regioselective two-step alkylation of easily-available diethyl 3-oxoglutarate (2) is described for the synthesis of racemates of the lactonic pheromones, la, lb, and 1c. Their (+)-enantiomers were also synthesized by means of microbiological reduction of the intermediary keto acids.
著者
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Kondo Hirokiyo
Department Of Biochemistry Okayama University Of Science
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Ozawa Hiroshi
Department Of Aerospace Engineering Nagoya University
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Hayashi Shuichi
Department Of Applied Chemistry. Faculty Of Engineering Toyama University
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Naoshima Yoshinobu
Department Of Agricultural Chemistry University Of Osaka Prefecture
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Kondo Hirokiyo
Department of Chemistry, Faculty of Science, OkayamaUniversity of Science
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Ozawa Hiroshi
Department of Chemistry, Faculty of Science, OkayamaUniversity of Science
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