Preparation of 14-, 18-, and 22-membered tetraaza macrocycles and their complexing ability for copper(II) and nickel(II) ions.
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概要
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14-,18-, and 22-membered tetraaza macrocycles have been prepared by the reaction of acetylacetone with ethylenediamine, 1,4-butanediamine, or 1,6-hexanediamine, respectively. Their copper(II) and nickel(II) complexes were characterized by electronic and infrared spectroscopies. The 14-membered macrocycle forms a mononuclear copper(II) complex with a planar structure, whereas the 18-membered macrocycle forms a mononuclear copper(II) complex with a pseudo-tetrahedral structure, and the 22-membered macrocycle forms di- and trinuclear copper(II) complexes. The complexation and extraction abilities of these macrocycles toward copper(II) and nickel(II) ions are discussed.
- 公益社団法人 日本化学会の論文
著者
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Shono Toshiyuki
Department Of Applied Chemistry Faculty Of Engineering Osaka Institute Of Technology
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Wakita Hisanobu
Department Of Chemistry Faculty Of Science Fukuoka University
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Matsushita Takayuki
Department Of Materials Chemistry Faculty Of Science And Technology Ryukoku University
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Fujiwara Manabu
Department Of Material Chemistry Ryukoku University
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Fujiwara Manabu
Department of Chemistry, Faculty of Science, Fukuoka University
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