Effect of plasticizer on the selectivity of potassium-selective PVC membrane electrodes based on bis(crown ether)s.
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概要
- 論文の詳細を見る
Potassium-selective PVC membrane electrodes based on bis(crown ether)s containing benzo-15-crown-5 moiety were prepared, <I>o</I>-nitrophenyl octyl ether (NPOE) or dipentyl phthalate (DPP) being used as a plasticizer. Selectivity coefficients for various monovalent ions were measured. The preference of potassium over sodium in the bis(crown ether) (I; <I>n</I>=5)–NPOE electrode system is close to that in the valinomycin system.
- 公益社団法人 日本化学会の論文
著者
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Shono Toshiyuki
Department Of Applied Chemistry Faculty Of Engineering Osaka Institute Of Technology
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Kimura Keiichi
Department Of Applied Chemistry Faculty Of Systems Engineering Wakayama University
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Tamura Hiroshi
Department Of Agricultural Chemistry Faculty Of Agriculture Niigata University
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Tamura Hiroshi
Department of Applied Chemistry, Faculty of Engineering, Osaka University
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Kimura Keiichi
Department of Applied Chemistry, Faculty of Engineering, Osaka University
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