Reactions of chloroiron(III) schiff base complexes with superoxide ion in dimethyl sulfoxide.
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概要
- 論文の詳細を見る
A series of monomeric chloroiron(III) complexes with the quadridentate or quinquedentate Schiff bases such as <I>N</I>,<I>N</I>′-disalicylideneethylenediamine or bis[3-(salicylideneamino)propyl]amine react with superoxide ions, O<SUB>2</SUB><SUP>−</SUP>, in dimethyl sulfoxide to give the corresponding μ-oxo dimers. The polymeric chloroiron(III) complexes with the polymeric (oligomeric) Schiff bases derived from 5,5′-methylenedisalicylaldehyde and triamines react with O<SUB>2</SUB><SUP>−</SUP> in dimethyl sulfoxide to give the oxygenated complexes, probably dioxygen adducts, Fe<SUP>III</SUP>–O<SUB>2</SUB><SUP>−</SUP>. This is suggested by the absorption spectra and the polarographic measurements.
- 公益社団法人 日本化学会の論文
著者
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Shono Toshiyuki
Department Of Applied Chemistry Faculty Of Engineering Osaka Institute Of Technology
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Nishino Mitsuru
Department Of Orthopaedic Surgery Kanazawa Medical University
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Matsushita Takayuki
Department Of Materials Chemistry Faculty Of Science And Technology Ryukoku University
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KONO Hiroshi
Department of Biomaterials Science, Graduate School of Medical and Dental Sciences, Kagoshima University
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Shono Toshiyuki
Department of Applied Chemistry, Faculty of Engineering, Osaka University
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Kono Hiroshi
Department of Applied Chemistry, Faculty of Engineering, Osaka University
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Matsushita Takayuki
Department of Architecture, Graduate School of Engineering,Kobe University
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