27Al NMR study on the interaction between aluminate and silicate ions in alkaline solution.
スポンサーリンク
概要
- 論文の詳細を見る
An interaction between aluminate and silicate ions in highly alkaline solution was investigated by a high-resolution <SUP>27</SUP>Al NMR study. The interaction greatly varied with alkali concentration, and did not occur at 1.0 mol dm<SUP>−3</SUP> NaOH. At 0.10 mol dm<SUP>−3</SUP> NaOH, the formation of a monomeric species with an ≡Al–O–Si≡ bond (Si/Al=1) was suggested and the formation constant was estimated to be 22.8 dm<SUP>3</SUP> mol<SUP>−1</SUP>. At 0.015 mol dm<SUP>−3</SUP> NaOH, polynuclear species with ≡Al–O–Si≡ bond was expected to be formed.
- 公益社団法人 日本化学会の論文
著者
-
YOKOYAMA Takushi
Department of Chemistry, Faculty of Science, Kyushu University
-
Yokoyama Takushi
Department Of Chemistry Faculty Of Science
-
Kinoshita Setsuko
Department Of Chemistry Faculty Of Science Fukuoka University
-
Wakita Hisanobu
Department Of Chemistry Faculty Of Science Fukuoka University
-
Tarutani Toshikazu
Department of Chemistry, Faculty of Science, Kyushu University
関連論文
- ガラスピード : 蛍光X線分析法によるアルミナークロム質耐火物中の各種成分の定量
- Temagami 産縞状鉄鉱床中の希土類元素の地球化学
- ガラスビード/蛍光X線分析法による炭化ケイ素含有耐火物中の酸化物成分の定量
- 地熱熱水から生成したシリカスケール中の希土類元素
- 佐賀県立九州シンクロトロン光研究センターにおける軟X線利用分析ビームライン(BL12)
- 酸化セリウムに吸着した金(III)化学種の吸着構造 : ^Au Mossbauer スペクトル及びEXAFSによる構造解析
- 境界構造を考慮した電子状態計算によるX線吸収端近傍構造の解析(ナノ空間と分析化学)
- 酸化セリウムに吸着された金化学種のキャラクタリゼーション
- 有機物質に対するYbイオン修飾酸化チタン光触媒上のYbイオンの効果
- 種々の有機化合物に対するランタニドイオン吸着酸化チタンの光触媒活性と触媒表面の構造解析
- 希土類金属吸着酸化チタン粉末の吸着構造と光触媒活性評価
- 学問と技術(ツール)
- 水酸化鉄(III)共沈法による金(III)錯イオンの濃縮と自動還元 : 電子製品廃棄物からの金回収への適用
- 同位体置換中性子回折法による室温から超臨界水中のイオンの水和構造
- Recent Development of the XANES Spectral Analysis Methods for the Structure Characterization of Metal Complexes in Solution
- Pre-edge Features of Ti K-edge X-ray Absorption Near-edge Structure for the Local Structure of Sol-Gel Titanium Oxides
- The Effect of UV Irradiation on the Reduction of Au(III) Ions Adsorbed on Manganese Dioxide
- Local Structure of Nitrogen Atoms in a Porphine Ring of meso-Phenyl Substituted Porphyrin with an Electron-Withdrawing Group Using X-ray Photoelectron Spectroscopy and X-ray Absorption Spectroscopy
- Electronic Structure Analysis of Iron(III)-Porphyrin Complexes by X-ray Absorption Spectra at the C, N and Fe K-Edges
- X-Ray Absorption Spectral Studies on the Anion-Selectivity of a Ruthenium(II) Polypyridine Complex-Impregnated Polymer Ultrathin Film
- X-ray Absorption Spectral Analyses by Theoretical Calculations for TiO_2 and Ni-Doped TiO_2 Thin Films on Glass Plates
- ^F and ^Al NMR Study on the Formation of Al-EDTA Fluoride Complex in Aqueous Solution
- Siliceous deposits formed from geothermal water in Kyushu, Japan : II. Distribution and state of aluminum along the growth direction of the deposits
- 気相分解/全反射蛍光X線分析法によるシリコンウェハー上の軽元素分析
- 次世代産業を先導する軟X線分光分析技術の展開を支える軟X線応用科学研究会発足にあたって
- Local Structure around Iron(III) Ion in Lamprey Hemoglobin
- ひげの効用
- 新規トリアザ環銅(II)錯体の合成、構造と性質
- 1,4,7-tris (2-o-hydroxyphenylpropyl)-1,4,7-triazacyclononane を用いた銅 (II) 錯体の合成と構造解析
- (D)国際交流事業・外国人研究員等特別招へい(短期)研究成果報告 : Imure Toth
- シンクロトロン軟X線を用いたX線吸収端近傍構造解析
- Analytical Sciences 誌と次なる飛躍
- 金属水酸化物共沈法による金の回収--浅熱水性金鉱床生成機構に学ぶ (第19回:E-Wasteのリサイクル促進のための分離精製技術)
- 菱刈金鉱床中の希土類元素の地球化学
- μ-Hydroxo-μ-phenolato Dinuclear Zinc(II) and Nickel(II) Complexes Derived from Dinucleating Compartmental Ligands of "End-off" Type : Synthesis, Structures, and Properties
- Hydrolytic Activity of Zn^Zn^ and Zn^Ba^ Complexes toward Tri (p-nitrophenyl) Phosphate and Di (p-nitrophenyl) Phosphate: A Functional Model of Heterobimetallic Phosphodiesterase
- Concentration of Gold(I) Thiosulfate Complex Ions on the Surface of Alumina Gel and their Change in Chemical State : Preliminary Experiment in the Elucidation of the Formation Mechanism of Epithermal Gold Deposits
- EPMA-EXEFSによるアルミニウム酸化物の化学状態別2次元分布撮像方法
- ^C and ^Al NMR and Potentiometric Study on the Interaction between Aluminium Ions and Quinolic Acid in Acidic Aqueous Solutions
- ^C and ^AI NMR Study on the Interaction between Aluminium Ion and Iminodiacetic Acid in Acidic Aqueous Solutions
- ^Al and ^P NMR Study on the Formation of Al-NTA-(Phosphate)_n (n=1 or 2)Complexes in Aqueous Solution
- Determination of trace gold in rock samples by a combination of two-stage solvent extraction and graphite furnace atomic absorption spectrometry : The problem of iron interference and its solution
- Determination of gold in geothermal water by anion exchange and inductively coupled plasma mass spectrometry
- 八丁原地域の鉄に富む酸性の熱水から生じた珪酸質沈殿物中の金濃度
- Hydrolytic Function of a Hydroxo-Zn^Pb^ Complex toward Tris-p-nitrophenyl Phosphate:A Functional Model of Heterobimetallic Phosphatases
- JRRM800 標準物質系列の蛍光X線分析への適用とスピネル原料成分の定量
- 低希釈・低温融解ガラスビード/蛍光X線分析法によるケイ酸カルシウム-フッ化物複合材料中のフッ素の定量
- 福岡県における雨水の化学的特徴と銅製屋根から溶解した銅イオン濃度との関係
- イネ中の不思議なケイ酸の化学(セミナー「生体の温度・水分センサーの機能と構造」)
- かご型シルセスキオキサンと希土類イオンとの相互作用
- ^Al及び^P核磁気共鳴法による水溶液中のアルミニウム-クエン酸-リン酸三元錯体の検出
- シリカの溶解に及ぼす硫黄系オキソ酸陰イオンの影響
- 水溶液中における非晶質シリカの溶解に及ぼす亜硫酸ナトリウムの影響(「若手研究者の初論文」)
- 有価金属の自然界における濃集機構に学ぶリサイクル--鉄・マンガンによる貴金属の濃集・分離の可能性 (特別講演 [環境資源工学会]第126回例会 エネルギー・環境技術の最前線)
- 土壌溶液中のケイ酸濃度に及ぼす有機物の影響に関するモデル実験 : ピロリドン系モノマーとポリマーの比較
- Bio-deposition of Amorphous Silica by an Extremely Thermophilic Bacterium, Thermus spp.
- First Detection of a Silicic Acid Complex with a Catechol Derivative under Natural Conditions
- Interaction between Al^ and Acrylic Acid and Polyacrylic Acid in Acidic Aqueous Solution : A Model Experiment for the Behavior of Al^ in Acidified Soil Solution
- X線を用いた溶存化学種のキャラクタリゼーション
- ポストICCCシンポジウム福岡「溶液中の金属錯体への構造化学的反応機構論的アプローチ」を終えて
- 分析化学会活動の活性化
- 溶液のキャラクタリゼーション - 溶液の中の距離を測る -
- 実験室EXAFS装置
- 軟X線吸収分光法を用いた水溶液中のナトリウム及びマグネシウムイオンの溶存構造解析
- 低シリカ蓄積変異体イネlsi1におけるケイ酸処理による生長促進効果の解析
- 環境応答とバイオミネラリゼーション : 極限環境下における細菌の生存戦略
- The structure of nickel(II) bromide in highly concentrated aqueous solution by X-ray diffraction analysis.
- Kinetic and thermodynamic characterization of thermal pyridine liberation-anation reactions of bis(2,3-alkanedione dioximato)dipyridinecobalt(III) iodide in the solid state.
- An EXAFS investigation of the coordination structure of copper(II) ions in aqueous Cu(ClO4)2 and methanolic CuCl2 solutions.
- Preparation of 14-, 18-, and 22-membered tetraaza macrocycles and their complexing ability for copper(II) and nickel(II) ions.
- The kinetics of the polymerization of silicic acid.
- Polymerization of silicic acid adsorbed on iron(III) hydroxide.
- Estimation of isomer ratio of 2,3-alkanedione dioxime using high-resolution 13C NMR in the solid state.
- High-resolution 13C NMR spectra of trans-(CoIII(2,3-alkanedione dioximato)2(pyridine)2)I complexes in the solid state.
- X-ray diffraction study on the coordination structure of chlorocopper(II) complexes in highly concentrated methanolic CuCl2 solution.
- Study of the polymerization of silicic acid adsorbed on iron(III) hydroxide by trimethylsilylation-gas chromatography.
- Polymerization of silicic acid adsorbed on aluminium hydroxide.
- Electron spin resonance and some spectral studies on coordination behaviors of paramagnetic metal ions for chelation resins.
- Spectrophotometric determination of silicic acid by flow injection analysis.
- The Synthesis of Crystalline Rare Earth Carbonates
- The synthesis of hydrated rare earth carbonate single crystals in gels.
- Chemical Studies of Minerals Containing Rarer Elements from the Far East District. LXIV. Abukumalite from Fusamata, Kawamata-machi, Fukushima Prefecture, Japan
- Coordination structure of Cu2+ ion in highly concentrated aqueous CuBr2 solution, determined by X-ray diffraction analysis.
- 27Al NMR study on the interaction between aluminate and silicate ions in alkaline solution.
- Formation of Gold Clusters on La–Ni Mixed Oxides and Its Catalytic Performance for Isomerization of Allylic Alcohols to Saturated Aldehydes
- ^C and ^ Al NMR Study of Complexation between Aluminium Ion and Simple Dicarboxylic Acids under an Acidic Condition : New Peak Assignments of ^ Al NMR Spectra of Mixed Solutions of Al^ and Simple Dicarboxylic Acids