On the reaction of N-(diphenylphosphinyl)-1-phenylethanimine with aromatic aldehydes giving 4-aryl-2,6-diphenylpyridine derivatives.
スポンサーリンク
概要
- 論文の詳細を見る
<I>N</I>-(Diphenylphosphinyl)-2-phenyl-1-azaallyl anion (<B>1</B>), generated from <I>N</I>-(diphenylphosphinyl)-1-phenylethanimine, reacted with aromatic aldehydes in a 2 : 1 molar ratio to give 4-aryl-2,6-diphenylpyridines in moderate yields. The intervention of <I>N</I>-phosphinyl-1-azadiene intermediates is proposed on the basis of the independent synthesis of an <I>N</I>-phosphinyl-1-azadiene and its conversion into a pyridine by the reaction with <B>1</B>.
- 公益社団法人 日本化学会の論文
著者
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Kato Hiroshi
Department Of Applied Biological Chemistry Graduate School Of Agricultural And Life Sciences The Uni
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Kobayashi Tomoshige
Department Of Chemistry Faculty Of Science Shinshu University
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Kakiuchi Hidetaka
Department of Chemistry, Faculty of Science, Shinshu University
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