Deamination of Methylenecyclopropylcarbinylamine. The Formation of a Vinyl Cation by Carbon-Carbon Bond Cleavage
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概要
- 論文の詳細を見る
The deamination of methylenecyclopropylcarbinylamine, prepared from ethyl methylenecyclopropanecarboxylate <I>via</I> the corresponding amide, gave acetylcyclopropane, methylenecyclopropylcarbinol, and 3-methylenecyclobutanol. On the basis of these results and the deuterium distribution of the deamination products of methylenecyclopropylcarbinylamine-α,α-d<SUB>2</SUB>, the homoallylic (III) and cyclopropylvinyl (VIII) cations are proposed as intermediates.
- 公益社団法人 日本化学会の論文
著者
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Kato Hiroshi
Department Of Applied Biological Chemistry Graduate School Of Agricultural And Life Sciences The Uni
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Nishimura Akio
Laboratory of Organic Chemistry, Tokyo Institute of Technology
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Ohta Masaki
Laboratorium für Organische Chemie, Tokio Institut für Technologies, Tokio
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