Synthesis of <I>trans</I>-Dibromo-bis{(2-pyridyl)methylamine} and -bis {<I>S</I>-1-(2-pyridyl)ethylamine} cobalt(III) Complexes
スポンサーリンク
概要
- 論文の詳細を見る
Light green crystals of <I>trans</I>-dibromo-bis{(2-pyridyl)-methylamine} and -bis{<I>S</I>-1-(2-pyridyl) -ethylamine}cobalt(III) bromide have been prepared. The latter complex shows a circular dichroism (CD) spectrum enantiomeric with that of the corresponding <I>S</I>-propylenediamine complex in the first absorption band region.
- 公益社団法人 日本化学会の論文
著者
-
Suzuki Toshishige
Department Of Biomedical Engineering Institute Of Basic Medical Sciences University Of Tsukuba
-
Watanabe Yoshiko
Department Of Cardiology Nishitokyo Central General Hospital
-
Saito Kazuo
Department Chemistry Faculty Of Science Tohoku University
-
Fujita Junnosuke
Department of Chemistry Faculty of Science Osaka University
-
Watanabe Yoshiko
Department of Chemistry, Faculty of Science, Tohoku University
関連論文
- Endovascular stent grafting for abdominal aortic aneurysm
- PE-465 The Prevalence of Ischemic Heart Disease in Patients with Aortic Aneurysms and Arteriosclerosis Obliterans(Peripheral circulation/Vascular disease(05)(H),Poster Session(English),The 72nd Annual Scientific Meeting of the Japanese Circulation Society
- Gender Differences in Physical and Psychological Stress Responses among College Judoists Undergoing Weight Reduction
- Inductively Coupled Plasma Mass Spectrometry for the Determination of Platinum Accumulation in Human Non-Small Cell Lung Cancer Cell Lines
- An Enzyme-Linked Immunosorbent Assay (ELISA) for Measuring Human Erythrocytes Catalase
- Evaluation of the Efficacy of Left Internal Thoracic Artery Graft for Chronic Total Occlusion of Left Anterior Descending Artery
- The 5-HT_1A Receptor Agonist 8-Hydroxy-2-di-n-(propylamino)tetralin(8-OH-DPAT)Induces Hyperglucagonemia in Rats
- Serious duodenitis concomitant with graft dysfunction following renal transplantation
- Hydronephrosis in the early stage of pregnancy after renal transplantation
- Alteration in hippocampal and cerebral expression of glial fibrillary acidic protein following styrene exposure in rat
- Comment and Reply
- K-Ar dates of some Miocene volcanic rocks from the Yamagata area,Northeast Japan
- A K-Ar Investigation of the Chichibu Quartz Diorite and Some Discussions on Its Cooling History
- Paleomagnetic Study of Pleistocene Lavas and Dikes of the Zao Volcano Group, Japan
- Syntheses, Structures and Spectroscopic Properties of Mixed-Ligand Chromium(III) Complexes Containing 1,2-Bis(dimethylphosphino)-ethane, 1,3-Bis(dimethylphosphino)propane or 1,1,1-Tris(dimethyl-phosphinomethyl)ethane
- The Twelve-Item General Health Questionnaire Among Japanese Workers
- An Urban Noise Survey in Sapporo, Japan
- Flow visualization of microcirculation in solid tumor tissues : intravital microscopic observation of blood circulation by use of a confocal laser scanning microscope
- Direct and indirect effects of electrical stimulation on the motility of human sperm
- Effect of reactive oxygen species in semen on the pregnancy of infertile couples
- Long-term results of second-stage thoracic endovascular aortic repair following total aortic arch replacement
- Hybrid Procedures Combining Conventional and Thoracic Endovascular Aortic Repair for Thoracic Aortic Aneurysms
- Simultaneous Multi-Determination of Brain Trace Element Concentrations by Inductively Coupled Plasma Mass Spectrometry
- Evolution of the Komiji Syncline in the North Fossa Magna, central Japan : Paleomagnetic and K-Ar age insights
- Note on the Third Excited Level of ^Hg
- A New Palladium(I) Dinuclear Complex Forming a Coplanar Structure for Two Coordination Planes
- Pelioid-Type Well-Differentiated Hepatocellular Carcinoma in a Patient with a History of Taking Oral Contraceptives : Report of a Case
- A High Density Sampling K-Ar Dating of the Kinpu-San Plutonic Body and the Initiation of the Philippine Sea Plate Subduction
- Rare gas studies of twenty-four antarctic chondrites
- Excess Ar in Some Metamorphic and Plutonic Rocks and Reduction of Thermal Neutron-induced ^Ar by Cd Shielding
- Development of a Computer Mapping System and an Application for the Purpose of Epidemiological Studies in Northern Japan
- What Should We Teach ? : The Elements-The Most Fundamental Concept of Chemistry
- Trace Elements and Neurotransmitters in the Brain under Stress
- Dynamics of Trace Elements in Human Body and Diseases
- K-Ar dating studies of Ashigawa and Tokuwa granodiorite bodies and plutonic geochronology in the South Fossa Magna, central Japan
- Miocene intra-arc bending at an arc-arc collision zone, central Japan
- The Presence of Heavy Metals in Urban Snow
- X-ray structural studies of green and brown crystals of trans-(CoC)2(N48))X(N48=1,4,7,10-tetraazacyclopentadecane, X=NO3-, BF4-, and ClO4-).
- Preparation and stereochemistry of cobalt(III) complexes containing 1,1,11,11-tetraphenyl-4,8-diaza-1,11-diphosphaundecane or (3S,9S)-3,9-dimethyl-1,1,11,11-tetraphenyl-4,8-diaza-1,11-diphosphaundecane, (C6H5)2CHRNHCH2CH2CH2NHCHRCH2P(C6H5)2 (R=H or CH3).
- Preparation and stereochemistry of cobalt(III) complexes containing 2,11-diphenyl-5,8-diaza-2,11-diphosphadodecane or (4S,9S)-4,9-dimethyl-2,11-diphenyl-5,8-diaza-2,11-diphosphadodecane, (C6H5)(CH3)PCH2CHRNHCH2CH2NHCHRCH2P(CH3)(C6H5) (R=H or CH3).
- EFFECT OF THE MORPHOLOGY OF SBS MODIFIED ASPHALT ON MECHANICAL PROPERTIES OF BINDER AND MIXTURE
- Infrared Spectroscopic Studies of Hexammine- and Pentammine-chromium(III) Complexes
- Preparation and characterization of optically active Schiff base-oxovanadium(IV) and -oxovanadium(V) complexes and catalytic properties of these complexes on asymmetric oxidation of sulfides into sulfoxides with organic hydroperoxides.
- Stopped-flow investigation of antioxidant activity of tocopherols.
- Preparation and characterization of rhodium(III) complexes containing (2-aminoethyl)dimethylphosphine (edmp) or 1,2-bis(dimethylphosphino)ethane (dmpe). Structures of fac-[Rh(edmp)3]3+, trans(Cl,Cl),cis(P,P)-[RhCl2(edmp)2]+, and trans-[RhCl2(dmpe)2]+.
- Green and brown isomers of the ((S)-1-amino-2-propanethiolato-N,S)(1,4,7,10-tetraazacyclododecane)cobalt(III) ion and crystal structure of the green isomer.
- Cobalt(III)-peroxo complexes containing 1,2-bis(dimethylphosphino)ethane (dmpe) or 1,3-bis(dimethylphosphino)propane (dmpp). Molecular structures of (Co(O2)(dmpe)2)B(C6H5)4 and (Co(O2)(dmpp)2)BF4H2O.
- Preparation, resolution, and absorption and circular dichroism spectra of (Co(en)n{NH2CH2CH2P(CH3)2}3-n)3+ and the related complexes, and the absolute configuration of (+)589-fac-(Co{NH2CH2CH2P(CH3)2}3)3+ determined by X-ray analysis.
- タイトル無し
- Effects of serotonin on blood glucose and insulin levels of glucose- and streptozotocin-treated mice.
- Preparation and X-Ray Crystal Structure of trans-Dinitro(1,4,7,10)-tetraazacycloheptadecane)cobalt(III) Tetrafluoroborate, trans-(Co(NO)2)2(N410))BF4.
- Preparation and electronic spectra of dichlorobis(1,10-phenanthroline)-molybdenum(III) and dichlorobis(2,2'-bipyridine)molybdenum(III) ions.
- Preparation and molecular structure of cis-.BETA.,trans(sec-N,P)-{(2-aminoethyl)dimethylphosphine}(3,7-diazanonane-1,9-diamine)cobalt(III) bromide dihydrate.
- Preparation and characterization of (CoX2(edpp)2)+(edpp=NH2CH2CH2P(C6H5)2,X=Cl-,Br-,I-,NCO-,NCS-,N3-,NO2-) and (CoX2(en)(dppe))+(en=NH2CH2CH2NH2,dppe=(C6H5)2PCH2CH2P(C6H5)2,X=Cl-,Br-,NCS-). Crystal structures of trans(NCS,NCS),cis(P,P)-(Co(NCS)2(edpp)2)Br
- Preparation and characterization of (Co(acetylacetonato)(diamine or 2,2'-bipyridyl)(aminoalkylphosphine))2+. Crystal structure of (+)5C3D1-.LAMBDA.-fac(N)-(acetylacetonato){(1R,2R)-1,2-cyclohexanediamine}{(2-aminoethyl)diphenylphosphine}cobalt(III) perchl
- Absorption, circular dichroism, and nuclear magnetic resonance studies of bis(acetylacetonato)cobalt(III) complexes containing 2-aminoalkylphosphine chelates with phosphorus and nitrogen donor atoms.
- A Proton Magnetic Resonance Study of Cobalt(III) Complexes Containing 1,10-Phenanthroline and Ethylenediamine
- Metal complexes of EDTA and its related compounds. II. Geometric isomers of [Co(X)(trimethylenediamine-N,N,N'-triacetate)] complexes with X=H2O, NH3, Cl-, and CN-.
- Preparation and absorption and circular dichroism spectra of cobalt(III) complexes with N,N,N',N'-tetrakis(2-aminoethyl)-1,2-ethanediamine,-1,3-propanediamine,-1,4-butanediamine,and -(R,R)- and -(R,S)- 2,4-pentanediamine.
- Cis to trans photoisomerization of [CoCl2{(CH3)2PCH2CH2CH2P(CH3)2}2]+, [CoCl(H2O){(CH3)2PCH2CH2P(CH3)2}2]2+ and related complexes.
- Structures of three diastereomers of trans(N-Ph, N-Ph)-2,4-pentanedionatobis(N-phenylethylenediamine)cobalt(III) and of one diastereomer of trans(N-Ph, N-Ph)-oxalatobis(N-phenylethylenediamine)cobalt(III) complex cations.
- Circular Dichroism Spectra of Cobalt(III) Complexes Containing Amino-Alcohols
- Metal Complexes Containing Six-Membered Chelate Rings. I. Preparation and Structure of 2,4-Pentanediaminetetraacetato Complexes of Cobalt(III)
- Substituent group electronic effects on inversion and proton-exchange rates at chiral nitrogen centers for a series of bis(.BETA.-diketonato)-(N-methylethylenediamine)cobalt(III) complexes.
- Structure and Homogeneous Chemical Equilibria of Lithium .BETA.-Diketonates in Dimethyl Sulfoxide.
- Preparation and characterization of cis- and trans-(RhCl2(dmap)2)+ (dmap=1,3-bis(dimethylarsino)propane), and X-ray structure analyses of these complexes and trans-(CoCl2(dmap)2)+.
- Preparation and stereochemistry of cobalt(III) complexes containing -3,8-dimethyl-1,1,10,10-tetraphenyl-4,7-diaza-1,10-diphosphadecane or -2,4,9,11-tetramethyl-5,8-diaza-2,11-diphosphadodecane (SS-Me2-mm-PNNP). Molecular structure of (+)589-.LAMBDA.-cis.B
- Preparation and Characterization of Cobalt(III), Nickel(II), and Copper(I) Complexes Containing 5,8-Diphenyl-5,8-diphospha-2,11-dithiadodecane (L), CH3SCH2CH2P(C6H5)CH2CH2P(C6H5)CH2CH2SCH3, and Molecular Structure of (Ni(rac(P)-L)2)(BF4)2.
- Preparation and crystal structure of bis((2-aminoethyl)dimethylphosphine)(1,2-bis(dimethylphosphino)ethane)cobalt(III) tribromide dihydrate, (Co{NH2CH2CH2P(CH3)2}2{(CH3)2PCH2CH2P(CH3)2})Br32H2O.
- Geometrical isomerization of .MU.-peroxo-bis(diethylenetriamine-(R)-propylenediaminecobalt(III)) ions via labile cobalt(II) species.
- X-Ray structures of di-.MU.-oxo, .MU.-oxo-.MU.-thio-, and di-.MU.-thio-.MU.-((R)-propylenediaminetetraacetato)-bis(oxomolybdate(V)) ions.
- Circular dichroism spectra and their relation to asymmetric distortion of some dimeric molybdenum(V) complexes containing optically active amino carboxylate.
- Diastereomers and circular dichroism spectra of the tris(trans-1,2-cyclopentanediamine)cobalt(III) complex.
- Preparation and stereochemistry of cobalt(III) complexes with tetramines derived from 1-(2-pyridyl)ethylamine.
- Optical spectra of tocopheroxyl model radicals.
- Circular dichroism spectra of cobalt(III)-ammine complexes containing optically active 1,3-dipheny-1,3-propanediamine or 1,2-dipheny-1,2-ethanediamine.
- Preparation and circular dichroism of dichloro-(S)-2-(butylphenyl-phosphinomethyl)pyrrolidine-palladium(II)([PdCl2L]) and its related complexes, and the absolute configuration of [PdCl2L] determined by X-ray analysis.
- Racemization and Isotopic Exchange of Tris(acetylacetonato)silicon(IV) Perchlorate in Organic Solvents
- Isomerization and Racemization of the Tris(4,4'-dimethyl-2,2'-bipyridine N,N'-dioxide)chromium(III) Complex.
- Circular dichroism spectra of cobalt(III) complexes of the type, trans-[CoX2(1,3-diamine)2]n+(X=Cl-, CN-, or NH3).
- Chiral recognition in catalytic hydrogenation of .ALPHA.-acylaminoacrylic acids by cationic rhodium(I) complexes of chiral aminophosphines derived from (R,R)-1,2-cyclohexanediamine or (R)-1,2-propanediamine.
- Splitting of the 2nd d-d band of trans-(CoCl2N4)X-type complexes observed in the solid state at 113K.
- Preparation and stereochemistry of bis(1,10-phenanthroline)- and bis-(2,2'-bipyridine)chromium(III) complexes containing 2,2'-bipyridine N,N'-dioxide or its 3,3'-dimethyl derivative.
- Synthesis of trans-Dibromo-bis{(2-pyridyl)methylamine} and -bis {S-1-(2-pyridyl)ethylamine} cobalt(III) Complexes
- Optical resolution of (2-aminoethyl)butylphenylphosphine and the absolute configuration assigned on the basis of circular dichroism spectra of its palladium(II) complexes.
- A novel cationic optically active complex of platinum(II) containing 2-methyl-2-butene and o-benzenediamine. The circular dichroism spectrum and kinetics of olefin exchange.
- The Effects of the Serotonin1A Receptor Agonist Buspirone on the Blood Glucose and Pancreatic Hormones in Rats.
- A study of the ligand exchange reaction of tetrakis(.MU.-trifluoroacetato)dimolybdenum(II) in acetonitrile by 19F NMR spectroscopy.
- Platinum(II)-Olefin Complexes Containing Amino Acids. III. Optical Inversion and Substitution of Coordinated Olefins in Optically Active trans(N)-Chloro-L-prolinato-olefinplatinum(II) Complexes in Organic Solvents
- Syntheses and Stereochemistry of Optical Isomers of tris(2,4-Pentanediamine)cobalt(III) Complex
- Isotopic Exchange Kinetics between Dibenzoylmethane-14C and Its Tris-type Complex with Aluminium (III) in Tetrahydrofuran
- Isolation and circular dichroism of the isomers of dicyanobis((R,R)-1,2-cyclohexanediamine) and bis((S)-propylenediamine)cobalt(III) complexes.
- Studies of Mixed Cyano Cobalt(III) Complexes. IV. Preparation and Characterization of trans(O,X)-[Co(X)(aminoacidato)(diethylenetriamine)]+ Complexes with X=CN−, NO2−, or Cl−
- Stereoselective substitution of trans-2-butene for the S,S-2-butene in trichloro-S,S-2-buteneplatinate(II) in acetone.
- Inversion at selenium in (MIII(RSeCH2CH2NH2){N(CH2CH2NH2)3})3+(MIII=Co,Rh; R=CH3,CH3CH2,C6H5CH2) and (Co(CH3SeCH2COO){N(CH2CH2NH2)3})2+.
- Preparation, and structural and spectroscopic characterization of cobalt(III) phosphine complexes of the type, (Co(CN)4-2n(acac)n(P)2)(n-1)+ (acac=acetylacetonate ion, n=0,1,2, and P=P(CH3)x(C6H5)3-x, x=0,1,2,3).
- Isomers of the (2,4-pentanedionato)bis(N-phenylethylenediamine)cobalt(III) ion.
- The Preparation and the Structure of (1,9-Diamino-1,4,6,6,9-pentamethyl-3,7-diazanona-3-ene) (l-propylenediamine)nickel(II) Perchlorate
- Structure of Cobalt(III) Complexes of d-, l-, and meso-2,4-Pentanediaminetetraacetate
- Bypass vs. Endovascular Therapy of Infrapopliteal Lesions for Critical Limb Ischemia