Preparation and molecular structure of cis-.BETA.,trans(sec-N,P)-{(2-aminoethyl)dimethylphosphine}(3,7-diazanonane-1,9-diamine)cobalt(III) bromide dihydrate.

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概要

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• The reaction of <I>trans</I>-[CoCl<SUB>2</SUB>(2,3,2-tet)]<SUP>+</SUP>(2,3,2-tet: 3,7-diazanonane-1,9-diamine) with (2-aminoethyl)dimethylphosphine (edmp) afforded only one geometrical isomer of [Co(edmp)(2,3,2-tet)]<SUP>3+</SUP>, the structure of which was determined by X-ray analysis to have the <I>cis</I>-β,<I>trans</I>-(<I>sec</I>-<I>N</I>,<I>P</I>) configuration.

• 公益社団法人 日本化学会の論文

著者

• KASHIWABARA Kazuo

  Department of Chemistry, Faculty of Science, Nagoya University

• Kashiwabara Kazuo

  Department Of Chemistry Faculty Of Science Nagoya University

• Fujita Junnosuke

  Department of Chemistry Faculty of Science Osaka University

• Ito Tasuku

  Division of Applied Molecular Science, Institute for Molecular Science

• Ohishi Tomoji

  Department of Chemistry, Faculty of Science, Nagoya University

• Ito Haruko

  Division of Applied Molecular Science, Institute for Molecular Science

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