Optical resolution of cyclo-palladated (dimethylaminomethyl)ferrocene.

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概要

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• Cyclo-palladated (dimethylaminomethyl)ferrocene has been resolved into optically pure enantiomers <I>via</I> the (<I>S</I>)-proline derivatives. The absolute configuration is assumed by comparing the circular dichroism spectrum with that of similarly cyclo-palladated (<I>S</I>)-[1-(dimethylamino)ethyl]ferrocene of the known configuration. Several optically active derivatives of the cyclo-palladated (dimethylaminomethyl)ferrocene have been prepared and characterized.

• 公益社団法人 日本化学会の論文

著者

• Komatsu Takao

  Department Of Physics Kochi University

• Nonoyama Matsuo

  Department Of Chemistry Faculty Of Science Nagoya University

• Fujita Junnosuke

  Department of Chemistry Faculty of Science Osaka University

• Komatsu Takao

  Department of Chemistry, Faculty of Science, Nagoya University

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