Optical resolution of (2-aminoethyl)butylphenylphosphine and the absolute configuration assigned on the basis of circular dichroism spectra of its palladium(II) complexes.
スポンサーリンク
概要
- 論文の詳細を見る
(2-Aminoethyl)butylphenylphosphine was resolved with (+)<SUB>D</SUB>-di-μ-chlorobis[(<I>S</I>)-<I>N</I>,<I>N</I>-dimethyl-α-methylbenzylamine-2<I>C</I>,<I>N</I>]dipalladium(II), and the absolute configuration of the chiral phosphorus atom was assigned on the basis of the circular dichroism spectra of dichloro palladium(II) complexes with the resolved aminophosphine.
- 公益社団法人 日本化学会の論文
著者
-
Kashiwabara Kazuo
Department Of Chemistry Faculty Of Science Nagoya University
-
Kinoshita Isamu
Department Of Chemistry Graduate School Of Science Osaka City University
-
Fujita Junnosuke
Department of Chemistry Faculty of Science Osaka University
関連論文
- Introduction of Chirality to the Remote, Open Face of a Metalloporphyrin through Coordination to the Metal of a Specially Designed Pendant Arm
- Mononuclear to Tetranuclear Structural Transformation in Vanadyl Complexes of 3-Hydroxypyridine-2-carboxylic Acid (H_2hpic)
- meso-Tetraphenylporphyrin Having Hexa-maltosyl and Decyl Chain as an Amphiphilic Photosensitizer toward Photodynamic Therapy
- Synthesis and X-ray Analysis of Mn-Mo Mixed Metal Oxide Cluster Cluster with Cubic Framework
- Tetranuclear Mo_2Rh_2 Complexes Obtained from Reactions between Triple Cubane-Type Oxide Cluster [(Cp^*Rh)_4Mo_4O_] (Cp^*=η^5-C_5(CH_3)_5) and Methanethiol: [{Cp^*Rh(μ-SCH_3)_3MoO_2}_2(μ-O)] and [{Cp^*Rh(μ-SCH_3)_3MoO}_2(μ-X)(μ-Y)] (X, Y=O and X=O, Y=
- General Synthesis of Useful Chelating Reagents Having a Sugar Unit, 1, 3 - diamino - 2 - propyl β- D - Glucopyranoside and 1, 3 - Diamino - 2 - propyl α - D - Mannopyranoside
- Structural Diversity of Copper Complexes with 2,2'-Dipyridyldisulfide. From Dimer to Infinite Sheet Structure Both in Solid State and in Solution
- A Novel Type of Amidato Coordination : The Metallocycle Rh-Rh-NH-C(Me) = O
- Conversion of Rectangular Tetrasulfide Ligand in Tetrarhodium Complex, [{(RhCp^*)_2(μ-CH_2)_2}_2(μ_4-S_4)]^(Cp_*=η^5-C_5Me_5), into Disulfide Ligands in Dirhodium Complex, [(RhCp_*)_2(μ-CH_2)_2(μ-S_2)]by Chemical Reduction
- Synthesis and Characterization of (μ-Alkoxo)bis(μ-carboxylato)diruthenium Complexes, Na[Ru_2(dhpta)(μ-O_2CR)_2] (dhptaH_5 = 1,3-diamino-2-hydroxypropane tetraacetic acid). A Ruthenium Analogue of Model Systems for Iron-oxo Proteins
- Synthesis of Lantern-type Dinuclear Mixed-Metal Complex of Platinum(II) and Nickel(II)
- Manganese(II), Nickel(II), and Palladium(II) Complexes of a Terpyridine-Like Ligand Containing a Sulfur Linkage, and an Analogous NCN Pincer Palladium(II) Complex : Synthesis, Characterization, and Pd-Catalyzed Reactions
- A Novel Tetranuclear Iron (III) Complex Having L-Alanine Bridges and an Unprecedented (Fe_4 (O_2H) Core
- Synthesis and Crystal Structure of Bis-(1,1,1-tris(dimethylphosphinomethyl)ethane)iron(II) Tetrafluoroborate Dihydrate
- Syntheses, Structures and Spectroscopic Properties of Mixed-Ligand Chromium(III) Complexes Containing 1,2-Bis(dimethylphosphino)-ethane, 1,3-Bis(dimethylphosphino)propane or 1,1,1-Tris(dimethyl-phosphinomethyl)ethane
- Structure-Activity Relationship of Insulinomimetic Activity of Zinc(II) Complexes with Pyridine-2-sulfonic Acid Derivatives
- Syntheses and Crystal Structures of Bis(dimethyldithiocarbamato)-(4,6-diphenyl-4,6-diphosphanonane-1,9-diammonium)cobalt(III) and Chloro(4,9-diphenyl-4,9-diphosphadodecane-1,12-diamine)nickel(II) Complexes
- A Thiacalix[3]pyridine Copper(I) Complex as a Highly Active Catalyst for the Olefin Aziridination Reaction
- Observation of Halide-Induced Conformational Conversion of Dinuclear Copper Complexes Having a Tetradentate Polypyridine Ligand with a p-Xylene Backbone
- Prepartion and Characterization of Mononuclear Palladium(II) and Dinuclear Palladium(I) Complexes Containing a New Phosphine-Imine-Type Didentate Ligand, 8-(Dimethylphosphin) quinoline (Me_2Pqn). Molecular Structures of cis-[Pd(Me_2Pqn)_2](BF_4)_2 and [Pd
- A Geometrical Isomeric Pair of Novel Cobalt(III) Complexes Containing Diphenylphosphine:cis- and trans-[Co(dtc)_2(PHPh_2)_2]BF_4 (dtc = N,N-Dimethyldithiocarbamate)
- Preparation, Crystal Structures and Spectroscopic Properties of a Series of Cobalt(III) Phosphine Complexes: trans- and cis-[Co(dtc)_2(PMe_3_nPh_n)_2]^+ (dtc=N,N-Dimethyldithiocarbamate; n = 0,1,2 or 3)
- "Compressed" Icelike Structures between Molecular Films Comparable with Ice Phase III
- Crystal Structures of Cobalt(III)-Methyldiphenylphosphine Complexes. Co(III)-P Bond Lengths and Their Cleavares
- Preparation and Characterization of Nickel(II), Palladium(II), and Platinum(II) Complexes Containing (2-Aminoethyl)dimethylphosphine or the Related Didentate Phosphine Ligands
- Preparation and Structural Features of Cu(I)Cu(II) Coordination Polymers Obtained by Using Tripodal Complexes as Bridging Ligands
- A New Palladium(I) Dinuclear Complex Forming a Coplanar Structure for Two Coordination Planes
- X-ray structural studies of green and brown crystals of trans-(CoC)2(N48))X(N48=1,4,7,10-tetraazacyclopentadecane, X=NO3-, BF4-, and ClO4-).
- Preparation and stereochemistry of cobalt(III) complexes containing 1,1,11,11-tetraphenyl-4,8-diaza-1,11-diphosphaundecane or (3S,9S)-3,9-dimethyl-1,1,11,11-tetraphenyl-4,8-diaza-1,11-diphosphaundecane, (C6H5)2CHRNHCH2CH2CH2NHCHRCH2P(C6H5)2 (R=H or CH3).
- Preparation and stereochemistry of cobalt(III) complexes containing 2,11-diphenyl-5,8-diaza-2,11-diphosphadodecane or (4S,9S)-4,9-dimethyl-2,11-diphenyl-5,8-diaza-2,11-diphosphadodecane, (C6H5)(CH3)PCH2CHRNHCH2CH2NHCHRCH2P(CH3)(C6H5) (R=H or CH3).
- Infrared Spectroscopic Studies of Hexammine- and Pentammine-chromium(III) Complexes
- Preparation and characterization of optically active Schiff base-oxovanadium(IV) and -oxovanadium(V) complexes and catalytic properties of these complexes on asymmetric oxidation of sulfides into sulfoxides with organic hydroperoxides.
- Preparation and characterization of rhodium(III) complexes containing (2-aminoethyl)dimethylphosphine (edmp) or 1,2-bis(dimethylphosphino)ethane (dmpe). Structures of fac-[Rh(edmp)3]3+, trans(Cl,Cl),cis(P,P)-[RhCl2(edmp)2]+, and trans-[RhCl2(dmpe)2]+.
- Green and brown isomers of the ((S)-1-amino-2-propanethiolato-N,S)(1,4,7,10-tetraazacyclododecane)cobalt(III) ion and crystal structure of the green isomer.
- Cobalt(III)-peroxo complexes containing 1,2-bis(dimethylphosphino)ethane (dmpe) or 1,3-bis(dimethylphosphino)propane (dmpp). Molecular structures of (Co(O2)(dmpe)2)B(C6H5)4 and (Co(O2)(dmpp)2)BF4H2O.
- Preparation, resolution, and absorption and circular dichroism spectra of (Co(en)n{NH2CH2CH2P(CH3)2}3-n)3+ and the related complexes, and the absolute configuration of (+)589-fac-(Co{NH2CH2CH2P(CH3)2}3)3+ determined by X-ray analysis.
- タイトル無し
- Preparation and X-Ray Crystal Structure of trans-Dinitro(1,4,7,10)-tetraazacycloheptadecane)cobalt(III) Tetrafluoroborate, trans-(Co(NO)2)2(N410))BF4.
- Preparation and molecular structure of cis-.BETA.,trans(sec-N,P)-{(2-aminoethyl)dimethylphosphine}(3,7-diazanonane-1,9-diamine)cobalt(III) bromide dihydrate.
- Preparation and characterization of (CoX2(edpp)2)+(edpp=NH2CH2CH2P(C6H5)2,X=Cl-,Br-,I-,NCO-,NCS-,N3-,NO2-) and (CoX2(en)(dppe))+(en=NH2CH2CH2NH2,dppe=(C6H5)2PCH2CH2P(C6H5)2,X=Cl-,Br-,NCS-). Crystal structures of trans(NCS,NCS),cis(P,P)-(Co(NCS)2(edpp)2)Br
- Preparation and characterization of (Co(acetylacetonato)(diamine or 2,2'-bipyridyl)(aminoalkylphosphine))2+. Crystal structure of (+)5C3D1-.LAMBDA.-fac(N)-(acetylacetonato){(1R,2R)-1,2-cyclohexanediamine}{(2-aminoethyl)diphenylphosphine}cobalt(III) perchl
- Absorption, circular dichroism, and nuclear magnetic resonance studies of bis(acetylacetonato)cobalt(III) complexes containing 2-aminoalkylphosphine chelates with phosphorus and nitrogen donor atoms.
- A Proton Magnetic Resonance Study of Cobalt(III) Complexes Containing 1,10-Phenanthroline and Ethylenediamine
- Metal complexes of EDTA and its related compounds. II. Geometric isomers of [Co(X)(trimethylenediamine-N,N,N'-triacetate)] complexes with X=H2O, NH3, Cl-, and CN-.
- Preparation and absorption and circular dichroism spectra of cobalt(III) complexes with N,N,N',N'-tetrakis(2-aminoethyl)-1,2-ethanediamine,-1,3-propanediamine,-1,4-butanediamine,and -(R,R)- and -(R,S)- 2,4-pentanediamine.
- Cis to trans photoisomerization of [CoCl2{(CH3)2PCH2CH2CH2P(CH3)2}2]+, [CoCl(H2O){(CH3)2PCH2CH2P(CH3)2}2]2+ and related complexes.
- Structures of three diastereomers of trans(N-Ph, N-Ph)-2,4-pentanedionatobis(N-phenylethylenediamine)cobalt(III) and of one diastereomer of trans(N-Ph, N-Ph)-oxalatobis(N-phenylethylenediamine)cobalt(III) complex cations.
- Circular Dichroism Spectra of Cobalt(III) Complexes Containing Amino-Alcohols
- Metal Complexes Containing Six-Membered Chelate Rings. I. Preparation and Structure of 2,4-Pentanediaminetetraacetato Complexes of Cobalt(III)
- Substituent group electronic effects on inversion and proton-exchange rates at chiral nitrogen centers for a series of bis(.BETA.-diketonato)-(N-methylethylenediamine)cobalt(III) complexes.
- Preparation and characterization of cis- and trans-(RhCl2(dmap)2)+ (dmap=1,3-bis(dimethylarsino)propane), and X-ray structure analyses of these complexes and trans-(CoCl2(dmap)2)+.
- Preparation and stereochemistry of cobalt(III) complexes containing -3,8-dimethyl-1,1,10,10-tetraphenyl-4,7-diaza-1,10-diphosphadecane or -2,4,9,11-tetramethyl-5,8-diaza-2,11-diphosphadodecane (SS-Me2-mm-PNNP). Molecular structure of (+)589-.LAMBDA.-cis.B
- Preparation and Characterization of Cobalt(III), Nickel(II), and Copper(I) Complexes Containing 5,8-Diphenyl-5,8-diphospha-2,11-dithiadodecane (L), CH3SCH2CH2P(C6H5)CH2CH2P(C6H5)CH2CH2SCH3, and Molecular Structure of (Ni(rac(P)-L)2)(BF4)2.
- Preparation and crystal structure of bis((2-aminoethyl)dimethylphosphine)(1,2-bis(dimethylphosphino)ethane)cobalt(III) tribromide dihydrate, (Co{NH2CH2CH2P(CH3)2}2{(CH3)2PCH2CH2P(CH3)2})Br32H2O.
- Diastereomers and circular dichroism spectra of the tris(trans-1,2-cyclopentanediamine)cobalt(III) complex.
- Preparation and stereochemistry of cobalt(III) complexes with tetramines derived from 1-(2-pyridyl)ethylamine.
- Circular dichroism spectra of cobalt(III)-ammine complexes containing optically active 1,3-dipheny-1,3-propanediamine or 1,2-dipheny-1,2-ethanediamine.
- Preparation and circular dichroism of dichloro-(S)-2-(butylphenyl-phosphinomethyl)pyrrolidine-palladium(II)([PdCl2L]) and its related complexes, and the absolute configuration of [PdCl2L] determined by X-ray analysis.
- Isomerization and Racemization of the Tris(4,4'-dimethyl-2,2'-bipyridine N,N'-dioxide)chromium(III) Complex.
- Circular dichroism spectra of cobalt(III) complexes of the type, trans-[CoX2(1,3-diamine)2]n+(X=Cl-, CN-, or NH3).
- Chiral recognition in catalytic hydrogenation of .ALPHA.-acylaminoacrylic acids by cationic rhodium(I) complexes of chiral aminophosphines derived from (R,R)-1,2-cyclohexanediamine or (R)-1,2-propanediamine.
- Splitting of the 2nd d-d band of trans-(CoCl2N4)X-type complexes observed in the solid state at 113K.
- Preparation and stereochemistry of bis(1,10-phenanthroline)- and bis-(2,2'-bipyridine)chromium(III) complexes containing 2,2'-bipyridine N,N'-dioxide or its 3,3'-dimethyl derivative.
- Synthesis of trans-Dibromo-bis{(2-pyridyl)methylamine} and -bis {S-1-(2-pyridyl)ethylamine} cobalt(III) Complexes
- Optical resolution of (2-aminoethyl)butylphenylphosphine and the absolute configuration assigned on the basis of circular dichroism spectra of its palladium(II) complexes.
- A novel cationic optically active complex of platinum(II) containing 2-methyl-2-butene and o-benzenediamine. The circular dichroism spectrum and kinetics of olefin exchange.
- Platinum(II)-Olefin Complexes Containing Amino Acids. III. Optical Inversion and Substitution of Coordinated Olefins in Optically Active trans(N)-Chloro-L-prolinato-olefinplatinum(II) Complexes in Organic Solvents
- Syntheses and Stereochemistry of Optical Isomers of tris(2,4-Pentanediamine)cobalt(III) Complex
- The preparation and properties of cobalt(III) phosphine complexes containing nitrite and acetylacetonate ions.
- Studies of Mixed Cyano Cobalt(III) Complexes. IV. Preparation and Characterization of trans(O,X)-[Co(X)(aminoacidato)(diethylenetriamine)]+ Complexes with X=CN−, NO2−, or Cl−
- Inversion at selenium in (MIII(RSeCH2CH2NH2){N(CH2CH2NH2)3})3+(MIII=Co,Rh; R=CH3,CH3CH2,C6H5CH2) and (Co(CH3SeCH2COO){N(CH2CH2NH2)3})2+.
- Preparation, and structural and spectroscopic characterization of cobalt(III) phosphine complexes of the type, (Co(CN)4-2n(acac)n(P)2)(n-1)+ (acac=acetylacetonate ion, n=0,1,2, and P=P(CH3)x(C6H5)3-x, x=0,1,2,3).
- Isomers of the (2,4-pentanedionato)bis(N-phenylethylenediamine)cobalt(III) ion.
- The Preparation and the Structure of (1,9-Diamino-1,4,6,6,9-pentamethyl-3,7-diazanona-3-ene) (l-propylenediamine)nickel(II) Perchlorate
- Structure of Cobalt(III) Complexes of d-, l-, and meso-2,4-Pentanediaminetetraacetate
- Preparation and properties of cobalt(III)-1,2-bis(dimethylphosphino)ethane (dmpe) complexes of the [Co(L)(dmpe)2]n+ type.
- Preparation, resolution, and spectroscopic properties of bis((2-aminoethyl)diphenylphosphine)- and (ethylenediamine)(1,2-bis(diphenylphosphino)ethane)-cobalt(III) complexes of acetylacetonate, malonate, oxalate, and carbonate ions.
- Optical resolution of cyclo-palladated (dimethylaminomethyl)ferrocene.