Metal complexes of EDTA and its related compounds. II. Geometric isomers of [Co(X)(trimethylenediamine-N,N,N'-triacetate)] complexes with X=H2O, NH3, Cl-, and CN-.

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概要

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• Three geometric isomers, equatorial-skew, polar-chair and polar-skew, of [Co(X)(trdtra)] (trdtra<SUP>3−</SUP>=trimethylenediamine-<I>N</I>,<I>N</I>,<I>N</I>′-triacetate) have been prepared for each X=H<SUB>2</SUB>O, NH<SUB>3</SUB> and Cl<SUP>−</SUP>, and the structures assigned mainly by comparing their electronic spectra with those of the equatorial-skew and the polar-chair isomers of <I>N</I>-methyl-trdtra complexes reported previously. The cyano complex gives only the polar-chair isomer.

• 公益社団法人 日本化学会の論文

著者

• Ogino Hiroshi

  Department Of Chemistry Faculty Of Science Tohoku University

• Saito Kazuo

  Department Chemistry Faculty Of Science Tohoku University

• Fujita Junnosuke

  Department of Chemistry Faculty of Science Osaka University

• Doh Myung-Ki

  Department of Chemistry, Faculty of Science, Nagoya University

• Doh Myung-Ki

  Department of Chemistry, Faculty of Science, Tohoku University

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