Geometrical isomerization of .MU.-peroxo-bis(diethylenetriamine-(R)-propylenediaminecobalt(III)) ions via labile cobalt(II) species.

スポンサーリンク

概要

• 論文の詳細を見る

• The title complex ion undergoes slow geometrical isomerization. A mechanism involving labile cobalt(II) species which is in equilibrium with the title ion, is suggested.

• 公益社団法人 日本化学会の論文

著者

• Sasaki Yoichi

  Department Of Chemistry Faculty Of Science Hokkaido University

• Saito Kazuo

  Department Chemistry Faculty Of Science Tohoku University

• Tachibana Masahiko

  Department of Chemistry, Faculty of Science, Tohoku University

関連論文

• Synthesis and Characterization of (μ-Alkoxo)bis(μ-carboxylato)diruthenium Complexes, Na[Ru_2(dhpta)(μ-O_2CR)_2] (dhptaH_5 = 1,3-diamino-2-hydroxypropane tetraacetic acid). A Ruthenium Analogue of Model Systems for Iron-oxo Proteins
• Vertically Linked Ruthenium(II) Porphyrin Oligomers
• Gender Differences in Physical and Psychological Stress Responses among College Judoists Undergoing Weight Reduction
• Mixed Chromium(III)-Ruthenium(III) Trinuclear Complex, [CrRu_2(μ_3-O)(μ-CH_3COO)_6(pyridine)_3]^+
• Inductively Coupled Plasma Mass Spectrometry for the Determination of Platinum Accumulation in Human Non-Small Cell Lung Cancer Cell Lines
• An Enzyme-Linked Immunosorbent Assay (ELISA) for Measuring Human Erythrocytes Catalase
• Structure and Vibrational Spectra of Trinuclear Metal Cluster Complexes. A Question of Symmetry
• Dinuclear Rhenium(III) Complexes with a Single Oxide Bridge, [Re_2(μ-O)Cl_2(L)_2]^ (L=2,2'-Bipyridine or 1,10-Phenanthroline)
• Dinuclear Oxomolybdenum(V) and Oxotungsten(V) Complexes of the Hexadentate Ligands N,N,N',N'-Tetrakis(2-pyridylmethyl)ethylenediamine and Its Propylenediamine Analog
• Preparation of Oxo-Bridged Dinuclear Iron(III) Complexes with One or Two O,O'-Bridged Optically Active Amino Acids
• Oxygen Atom Transfers from μ-Oxo-bis(Oxomolybdenum(V) Porphyrin) to Chromium(II) Porphyrins in Toluene
• Preparation and Electrochemical Response of Poly(4-vinylpyridine)- Coordinated Oxo-acetato Triruthenium Cluster Film
• Synthesis of Trinuclear Molybdenum Cluster Complex with Novel Skeleton, [Mo_3(μ_3-CCH_3)(μ_3-O)(μ-C_6H_5COO)_6(CH_3OH)_3]Cl
• Serious duodenitis concomitant with graft dysfunction following renal transplantation
• Hydronephrosis in the early stage of pregnancy after renal transplantation
• Alteration in hippocampal and cerebral expression of glial fibrillary acidic protein following styrene exposure in rat
• Comment and Reply
• K-Ar dates of some Miocene volcanic rocks from the Yamagata area,Northeast Japan
• A K-Ar Investigation of the Chichibu Quartz Diorite and Some Discussions on Its Cooling History
• Paleomagnetic Study of Pleistocene Lavas and Dikes of the Zao Volcano Group, Japan
• The Twelve-Item General Health Questionnaire Among Japanese Workers
• An Urban Noise Survey in Sapporo, Japan
• Direct and indirect effects of electrical stimulation on the motility of human sperm
• Effect of reactive oxygen species in semen on the pregnancy of infertile couples
• Simultaneous Multi-Determination of Brain Trace Element Concentrations by Inductively Coupled Plasma Mass Spectrometry
• Evolution of the Komiji Syncline in the North Fossa Magna, central Japan : Paleomagnetic and K-Ar age insights
• Note on the Third Excited Level of ^Hg
• A High Density Sampling K-Ar Dating of the Kinpu-San Plutonic Body and the Initiation of the Philippine Sea Plate Subduction
• Rare gas studies of twenty-four antarctic chondrites
• Excess Ar in Some Metamorphic and Plutonic Rocks and Reduction of Thermal Neutron-induced ^Ar by Cd Shielding
• Development of a Computer Mapping System and an Application for the Purpose of Epidemiological Studies in Northern Japan
• What Should We Teach ? : The Elements-The Most Fundamental Concept of Chemistry
• Trace Elements and Neurotransmitters in the Brain under Stress
• Dynamics of Trace Elements in Human Body and Diseases
• K-Ar dating studies of Ashigawa and Tokuwa granodiorite bodies and plutonic geochronology in the South Fossa Magna, central Japan
• Miocene intra-arc bending at an arc-arc collision zone, central Japan
• The Presence of Heavy Metals in Urban Snow
• EFFECT OF THE MORPHOLOGY OF SBS MODIFIED ASPHALT ON MECHANICAL PROPERTIES OF BINDER AND MIXTURE
• Maternal-to-Fetal Transfer of Ritodrine in Twin Pregnancy
• Preparation and Properties of Oxo-Centered Trinuclear Chromium(III) Complexes with Bridging Optically Active Amino Acids, (Cr3(.MU.3-O)(.MU.-O,O'-amino-acid)6(H2O)3)7+.
• Preparation and electronic spectra of dichlorobis(1,10-phenanthroline)-molybdenum(III) and dichlorobis(2,2'-bipyridine)molybdenum(III) ions.
• Metal complexes of EDTA and its related compounds. II. Geometric isomers of [Co(X)(trimethylenediamine-N,N,N'-triacetate)] complexes with X=H2O, NH3, Cl-, and CN-.
• Circular Dichroism Spectra of Cobalt(III) Complexes Containing Amino-Alcohols
• Metal Complexes Containing Six-Membered Chelate Rings. I. Preparation and Structure of 2,4-Pentanediaminetetraacetato Complexes of Cobalt(III)
• Geometrical isomerization of .MU.-peroxo-bis(diethylenetriamine-(R)-propylenediaminecobalt(III)) ions via labile cobalt(II) species.
• X-Ray structures of di-.MU.-oxo, .MU.-oxo-.MU.-thio-, and di-.MU.-thio-.MU.-((R)-propylenediaminetetraacetato)-bis(oxomolybdate(V)) ions.
• Circular dichroism spectra and their relation to asymmetric distortion of some dimeric molybdenum(V) complexes containing optically active amino carboxylate.
• Circular dichroism spectra of cobalt(III)-ammine complexes containing optically active 1,3-dipheny-1,3-propanediamine or 1,2-dipheny-1,2-ethanediamine.
• Racemization and Isotopic Exchange of Tris(acetylacetonato)silicon(IV) Perchlorate in Organic Solvents
• Synthesis of trans-Dibromo-bis{(2-pyridyl)methylamine} and -bis {S-1-(2-pyridyl)ethylamine} cobalt(III) Complexes
• A novel cationic optically active complex of platinum(II) containing 2-methyl-2-butene and o-benzenediamine. The circular dichroism spectrum and kinetics of olefin exchange.
• A study of the ligand exchange reaction of tetrakis(.MU.-trifluoroacetato)dimolybdenum(II) in acetonitrile by 19F NMR spectroscopy.
• Platinum(II)-Olefin Complexes Containing Amino Acids. III. Optical Inversion and Substitution of Coordinated Olefins in Optically Active trans(N)-Chloro-L-prolinato-olefinplatinum(II) Complexes in Organic Solvents
• Syntheses and Stereochemistry of Optical Isomers of tris(2,4-Pentanediamine)cobalt(III) Complex
• Isotopic Exchange Kinetics between Dibenzoylmethane-14C and Its Tris-type Complex with Aluminium (III) in Tetrahydrofuran
• Isolation and circular dichroism of the isomers of dicyanobis((R,R)-1,2-cyclohexanediamine) and bis((S)-propylenediamine)cobalt(III) complexes.
• Stereoselective substitution of trans-2-butene for the S,S-2-butene in trichloro-S,S-2-buteneplatinate(II) in acetone.
• Structure of Cobalt(III) Complexes of d-, l-, and meso-2,4-Pentanediaminetetraacetate

もっと見る 閉じる

スポンサーリンク