Some aspects on the mechanism of palladium-complex-catalyzed decomposition of and cyclopropanation with ethyl diazoacetate.
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概要
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Carbenoid decomposition of ethyl diazoacetate in the presence of various palladium complexes as catalysts was found to kinetically depend on the identity of halide ligands. The use of several chiral ligands did not induce appreciable enantioselective catalytic cyclopropanation between ethyl diazoacetate and styrene. The active catalyst species is not under the influence of the chiral ligands but under control of halides which are bound more strongly to the metal.
- 公益社団法人 日本化学会の論文
著者
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Koyama Teruhisa
Department Of Pediatrics National Hospital Organization Okayama Medical Center
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Nakamura Akira
Department Oc Macromolecular Science Faculty Of Science Osaka University
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Otsuka Sei
Department of Chemistry, Faculty of Engineering Science, and Department of Polymer Science, Faculty of Science, Osaka University
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