UV photoelectron spectroscopic investigation and the DV-X.ALPHA. MO calculation of tetrakis(2-methyl-2-propanethiolato)molybdenum(IV).
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概要
- 論文の詳細を見る
Helium(I) ultraviolet photoelectron spectrum is reported for the compound Mo(<I>t</I>-BuS)<SUB>4</SUB>. The observed spectrum is interpreted by means of DV-Xα MO calculations on the model compounds Mo(SH)<SUB>4</SUB> and Mo(SMe)<SUB>4</SUB>. The UV photoelectron spectrum of Mo(<I>t</I>-BuS)<SUB>4</SUB> exhibits a low ionization potential band (<I>IP</I>=6.43 eV) which corresponds to ionization of mainly Mo4d<SUB>z<SUP>2</SUP></SUB> electron of A<SUB>1</SUB> representation. This molecular orbital has also bonding character between Mo4d and S3d.
- 公益社団法人 日本化学会の論文
著者
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Takahashi Masao
Department Of Cardiovascular Medicine Graduate School Of Medicine University Of Tokyo
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Watanabe Iwao
Department Of Anesthesilogy Takasaki National Hospital
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Ikeda Shigero
Department Of Chemistry Faculty Of Science Osaka University
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Kamata Masato
Department of Chemistry, Faculty of Engineering Science, Osaka University
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Otsuka Sei
Department of Chemistry, Faculty of Engineering Science, Osaka University
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Otsuka Sei
Department of Chemistry, Faculty of Engineering Science, and Department of Polymer Science, Faculty of Science, Osaka University
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Takahashi Masao
Department of Chemistry, Faculty of Science, Osaka University
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