XPS study on the charge distribution in chromium(0) complexes.
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概要
- 論文の詳細を見る
Binding energies of core electrons in Cr(C<SUB>6</SUB>H<SUB>6</SUB>)<SUB>2</SUB>, Cr(C<SUB>6</SUB>H<SUB>6</SUB>)(CO)<SUB>3</SUB>, and Cr(CO)<SUB>6</SUB> were measured by means of X-ray photoelectron spectroscopic method in solid phase. By comparison with their UPS spectra observed in gasous phase, binding energies referred to vacuum level can be obtained. On the basis of this result, charge distribution in these complexes are estimated. The intramolecular relaxation energy of Cr(C<SUB>6</SUB>H<SUB>6</SUB>)<SUB>2</SUB> is also discussed.
- 公益社団法人 日本化学会の論文
著者
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Tamura Tadashi
Department Of Cardiology Jikei University School Of Medicine
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Watanabe Iwao
Department Of Anesthesilogy Takasaki National Hospital
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Yokoyama Yu
Department Of Chemistry Faculty Of Science Osaka University
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Ikeda Shigero
Department Of Chemistry Faculty Of Science Osaka University
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Kinomura Fumio
Department of Chemistry, Faculty of Science, Osaka University
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