X-Ray Photoelectron Spectroscopic Study of the Reaction of Evaporated Iron, Nickel, and Palladium with Nitric Oxide
スポンサーリンク
概要
- 論文の詳細を見る
The reaction of the evaporated iron, nickel, and palladium with NO was investigated by X-ray photoelectron spectroscopy. On both iron and nickel larger part of NO dissociates to give two or more N(1s) and O(1s) photoelectron peaks which are ascribable to the surface oxide, nitride, and NO species. The proportion of these species is estimated roughly from the intensity ratios of the N(1s) and O(1s) peaks at 15 NO: 65 O: 20 N (iron) and 7 NO: 65 O: 28 N (nickel) when the metals are exposed to 5 Torr of NO gasfor 1 s, and 35 NO: 55 O: 10 N (iron) and 10 NO: 75 O: 15 N (nickel) when exposed to 10 Torr of NO for 10 min. On palladium the N(1s) for chemisorbed NO is observed. The N(1s) binding energies of the surface NO are compared with the N(1s) binding energies and the infrared NO frequencies of the corresponding transition metal nitrosyls.
- 公益社団法人 日本化学会の論文
著者
-
Kishi Kosaku
Department Of Chemistry Osaka University
-
Ikeda Shigero
Department Of Chemistry Faculty Of Science Osaka University
関連論文
- Estimation of the Dissolved Structures and Condensation Reactivities of Mononuclear Molybdenum(VI) Species in Solution Using the UV-vis Absorption Spectra and Molecular Orbital Calculation DV-Xα
- An Upper Limit for the Probability of Nuclear Excitation by Electron Transition in U
- X-Ray Photoemission Spectra of Valence Bands in Amorphous Ge-Ni, Ge-Fe and Ge-Au Alloys
- Self-Scanning Photodiode Array as X-Ray Detector and Its Application to EXAFS
- Reproducibility Tests of Extended X-Ray Absorption Fine Structure for Aqua and Ammine Complexes of First Transition Metals in Solid and Aqueous Solution
- Photoionization threshold energies of amine solutions studied by photoelectron emission by solution.
- Preparation of tetraethylammonium hexamolybdate by the use of extraction method.
- He I photoelectron spectra of ethylene carbonate and related compounds.
- X-Ray Photoelectron Spectroscopic Study of the Reaction of Evaporated Iron, Nickel, and Palladium with Nitric Oxide
- XPS study on the charge distribution in chromium(0) complexes.
- Band shape of photoelectron spectrum and potential energy curve for alkylamine.
- Ultraviolet Study for the Adsorption of Acetylacetone on D-Tartaric Acid Preadsorbed Nickel Film
- Solvation of alkylbenzenes studied by photoelectron emission spectroscopy of organic solutions.
- UV photoelectron spectroscopic investigation and the DV-X.ALPHA. MO calculation of tetrakis(2-methyl-2-propanethiolato)molybdenum(IV).
- Lone Pair Ionization Potentials of Carboxylic Acids Determined by He(I) Photoelectron Spectroscopy
- Photoacoustic spectrometry of solid samples. III. Microdetermination of mercury as Hg diphenylcarbazone complex.
- Reduction of nitrobenzenes on thin aluminium oxide utilized in inelastic electron tunneling spectroscopy.
- Chemical shifts of sulfur KLL Auger electron energies in its compounds.
- Studies on the chemical shifts of Auger electron energies for magnesium and zinc in their compounds.