XANES of aqua complexes of 3d transition metals in solid and solution.
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概要
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A characteristic second peak appears at about 10 eV from a main peak in the XANES (X-ray Absorption Near Edge Structure) spectrum of aqueous 3d transition metal complex of divalent state. This second peak is prominent in solid samples. The peak intensity depends on the kind of central metal or counter anion in solid. Theoretical calculations based on the full multiple scattering formalism provide the information regarding the origin and property of the second peak in XANES. The second peak can be reproduced by the multiple scattering calculation considering only six first coordinating oxygen atoms. The intensity and the position of the peak vary with the charge on the first coordinating oxygen atoms which is affected by the ions or solvent molecules contacting with the metal complex.
- 公益社団法人 日本化学会の論文
著者
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Tashiro Kouji
Faculty Of Engineering Yokohama National University
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Miyanaga Takafumi
Department Of Advanced Physics Faculty Of Science And Technology Hirosaki University
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Watanabe Iwao
Department Of Anesthesilogy Takasaki National Hospital
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Ikeda Shigero
Institute of Science and Technology, Ryukoku University
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Fujiwara Takashi
Faculty of Engineering, Yokohama National University
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Tashiro Kouji
Faculty of Engineering, Yokohama National University
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