The Ullmann condensation reaction of haloanthraquinone derivatives with amines in aprotic solvents. IV. Kinetic studies of the condensation with ethylenediamine.
スポンサーリンク
概要
- 論文の詳細を見る
In the Ullmann condensation of bromoanthraquinones (AQBr) with ethylenediamine using copper(I) bromide as a catalyst, the reaction rate decreased with time which has been interpreted in terms of the formation of the ineffective copper(II) species. The kinetic investigation showed the reaction rate to be first order both for the copper(I) species and AQBr. After prolonged reaction the copper(I) species was quantitatively converted to the copper(II) species, the copper(II) species appearing to have little catalytic activity due to strong coordination with ethylenediamine. The reactivities of the haloanthraquinones were dependent on the ease of coordination with Cu(I) and the rate of Cu(II) formation. The mechanism, including the reaction between Cu<SUP>I</SUP>(AQBr) and ethylenediamine, has been proposed and discussed.
- 公益社団法人 日本化学会の論文
著者
-
Arai Sadao
Department Of Chemistry Tokyo Medical University
-
Yamagishi Takamichi
Department Of Applied Chemistry Graduate School Of Engineering Tokyo Metropolitan University
-
TANAKA Akira
Department of Agricultural Chemistry, Faculty of Agriculture, Tohoku University
-
Arai Sadao
Department of Industrial Chemistry, Faculty of Technology, Tokyo Metropolitan University
-
Hida Mitsuhiko
Department of Industrial Chemistry, Faculty of Technology, Tokyo Metropolitan University
-
Hida Mitsuhiko
Department of Industrial Chemistry, Faculty of Engineering, Tokyo Metropolitan University
関連論文
- PE-391 Low-Density Lipoprotein Subfraction as a New Risk Factor for Silent Laucnar Infarction in Patients with Essential Hypertension(Cerebrovascular circulation/Stroke-2, The 71st Annual Scientific Meeting of the Japanese Circulation Society)
- Arteriovenous Malformation in the Cerebellopontine Angle Presenting as Hemifacial Spasm : Case Report
- Effects of Mannitol on Microcirculation during Temporary Occlusion of the Middle Cerebral Artery in Cats
- Allelic Loss of 14q and 22q, NF2 Mutation, and Genetic Instability Occur Independently of c-kit Mutation in Gastrointestinal Stromal Tumor
- Metabolism of Pyrogallol to Purpurogallin by Human Erythrocytic Hemoglobin
- P-337 Synthesis and Activity of Acyl-substituted Catechin, Epicatechin and Procyanidin dimers
- University of Tokyo's CubeSat Project - Mission Concept and Subsystem Design -
- Tumor thrombi in the portal vein system originating from gastrointestinal tract cancer
- Treatment of ruptured hepatocellular carcinoma
- Peroxisome Proliferator-Activated Receptor α and γ Ligands Inhibit Expression ApolipoproteinB-48Receptor in Human monocytes and THP-1 Cells
- Spontaneous Cerebrospinal Fluid Leakage Detected by Magnetic Resonance Cisternography : Case Report
- Extensive Edema in the Thalamus Caused by Thrombosed Basilar Artery Aneurysm : Case Report
- Molecular Structure of 1, 3-Disubstituted π-Allyl Palladium (II) Complecxes with a Chiral Diphosphine : The Intermediate of Palladium-catalyzed Asymmetric Asymmetric Allylic Alkylation
- Isomerization of Imines Catalyzed by Ruthenium-Hydride Complexes
- Synthesis of (-)-cis-Neocnidilide(Organic Chemistry)
- Synthesis and Absolute Configuration of Neocnidilide(Organic Chemistry)
- Organogel Formation by Self-assembly of Ag(I) and Mono-urea Derivatives Containing Pyridyl Group
- Phenoxazine Compounds Produced by the Reactions with Bovine Hemoglobin Show Antimicrobial Activity Against Non-tuberculosis Mycobacteria
- Synthesis, Conformation, and Chemical Properties of New Mini Parallel Double-Stranded Peptides Conjugated with -Phe-Phe- and -Phe-Phe-X- Sequences
- Immediate-type hypersensitivity to pyridoxal 5'-phosphate: Study of in vivo and in vitro cross-reactivity and identification of the antigenic determinant
- Quantitative Determination of Sugars and Myo-Inositol in Citrus Fruits Grown in Japan Using High-Performance Anion-Exchange Chromatography
- Stability of Morphine Hydrochloride in a Total Parenteral Nutrient Solution
- High-performance liquid chromatographic-fluorimetric assay for cathepsin A (lysosomal protective protein) activity
- High-performance liquid chromatographic-colorimetric assay for glycine carboxypeptidase activity
- Effective Catalysts for Transfer Hydrogenation of Ketones and Imines by Propan-2-ol : Ruthenium-Hydride or Ruthenium-Dihydride Complexes
- Differences in Penetration Force of Intravenous Catheters : Effect of Grinding Methods on Inner Needles of Intravenous Catheters
- Accumulation of ^Tc-PMT in renal metastasis of hepatocellular carcinoma
- Extreme discrepancy between macroscopic diagnosis and pathological findings of gallbladder cancer treated by hepatopancreatoduodenectomy
- Extrahepatic large hepatocellular carcinoma with peritoneal dissemination : multimodal treatment, including four surgical operations
- Intravascular Tissue Velocity Imaging
- Correlation dimension analysis of the artificial circulation
- Treatment of multiple organ failure by a totally implantable ventricular assist device
- An automatic monitoring system for artificial hearts using a hierarchical self-organizing map
- Application of a shape memory alloy for internal artificial organs
- Autonomic nerve function with an artificial heart and ventricular assist device
- Development of Unusual Collateral Channel From the Posterior Meningeal Artery After Endovascular Proximal Occlusion of the Posterior Inferior Cerebellar Artery
- Rebleeding After Endovascular Embolization of Ruptured Cerebral Aneurysms
- Spasm induced by protection balloon during carotid artery stenting
- Cerebral Protection During Retrograde Carotid Artery Stenting for Proximal Carotid Artery Stenosis : Technical Note
- Hyperform Remodeling Balloon for the Balloon Occlusion Test of Persistent Primitive Trigeminal Artery Aneurysm : Case Report
- Retrograde Carotid Stenting for Isolated Stenosis of the Proximal Common Carotid Artery : Case Report
- Improved Cerebral Perfusion After Simultaneous Stenting for Tandem Stenoses of the Internal Carotid Artery
- Dural AVFs of the Cavernous Sinus : Transvenous Embolization Using a Direct Superficial Temporal Vein Approach
- Internal Carotid Aneurysms Presenting with Mass Effect Symptoms of Cranial Nerve Dysfunction : Efficacy and Limitations of Endosaccular Embolization with GDC
- Endovascular Treatment of Anterior Cerebral Artery Aneurysms Using Guglielmi Detachable Coils : Mid-term Clinical Evaluation
- Aberrant Right Subclavian Artery
- Duplication of Distal Part of the Basilar Artery
- Spontaneous Thrombosis of a Giant Intracavernous Internal Carotid Artery Aneurysm and Ipsilateral Internal Carotid Artery Occlusion
- Rapid Expansion of Benign Scalp Neurofibroma Caused by Massive Intratumoral Hemorrhage : Case Report
- Activation of Fronto-Limbic System in the Human Brain by Cigarette Smoking : Evaluated by a CBF Measurement
- Diagnostic Value of Perfusion MRI in Classifying Stroke
- Jejunal interposition following proximal gastrectomy for early gastric cancer : effect on the quality of life
- Synthesis and Biological Activity of (±)-Pyrenolide B(Organic Chemistry)
- Syntheses of Ruthenium(II) Complexes with Pentadentate Ligands and Catalytic Oxidation of Alkane Using 2,6-Dichloropyridine N-Oxide
- DNA Topology on an Increase in Positive Writhing Number of DNA : Conformation Changes in the Time Course of cis-Diamminedichloroplatinum(II)-DNA Adducts
- Association Constants of Ferrocene with Cyclodextrins in Aqueous Medium Determined by Solubility Measurements of Ferrocene
- Dilution by Physiological Saline Deteriorates Color Discrimination of Arterial and Venous Blood
- Synthesis of HS-toxin A Aglycone
- Back Propagation Learning Using a Super Stable Motion
- Solid-state Photopolymerization of Diacetylene-containing Carboxylates with Naphthylmethylammonium as the Countercation in a Two-dimensional Array
- Atypical liver hemangioma with shunt : long-term follow-up
- Fibroblast Growth Factor-2 Accelerates Invasion of Oral Squamous Cell Carcinoma
- Synthesis of (-)-Muricatacin
- Prediction of Endocrine Disruptors Based on a New Structure-Activity Relationship for Sex and Environmental Hormones Using Chemical Hardness Concept
- C-kit Gene Abnormalities in Gastrointestinal Stromal Tumors (Tumors of Interstitial Cells of Cajal)
- Diastereomeric Selective Effects for Growth Inhibition of Synthesized Mini Parallel Double-Stranded Peptides on Escherichia coli and Staphylococcus aureus
- Topology Effect for DNA Structure of Cisplatin : Topological Transformation of Cisplatin-Closed Circular DNA Addusts by DNA Topoisomerase I
- Hardness Controlled Enzymes and Electronegativity Controlled Enzymes : Role of an Absolute Hardness-Electronegativity (η-χ) Activity Diagram as a Coordinate for Biological Activities
- Total Synthesis of (-)-Decarestrictine J
- A Long Course of Leukocytopenia and Splenomegaly with Extramedullary Hematopoiesis in the Absence of Clinically Manifested Rheumatoid Arthritis
- Effects of Oxygen Gas Annealing on Electrical Properties and Internal Stress in Indium Tin Oxide Films : Semiconductors
- PE-324 Pitavastatin Inhibits Remnant Lipoprotein-induced Macrophage Foam Cell Formation via ApoB48 Receptor-dependent Mechanism(Atherosclerosis, Basic 5 (IHD) : PE55)(Poster Session (English))
- OJ-195 Sphingosine 1-phosphate induced monocyte-endothelial interaction involves PKC and RhoA dependent mechanism(Atherosclerosis, Basic 2 (IHD) : OJ22)(Oral Presentation (Japanese))
- Molecular Aggregation and Ultrasonic Properties of Hydroxypropyl-Cellulose Films
- ピレンおよびベリレンπ-ラジカルカチオンへの求核置換反応によるピリジウム共役組織体の電解合成
- Nymphal Development of the German Cockroach, Blattella germanica LINNE (Blattaria : Blattellidae), with Special Reference to Instar Determination and Intra-Instar Staging
- Undifferentiated Carcinoma of the Common Bile Duct with Intraductal Tumor Thrombi : Report of a Case
- Use of STA-MCA Anastomosis for Clipping of Giant Middle Cerebral Artery Aneurysm : Case Report
- Usefulness of indicators for stability of masticatory movement path
- Synthesis of Optically Pure (R)-4a-Methyl-4,4a,5,6,7,8-hexahydro-2(3H)-naphthalenone and Its Transformation into (+)-7-Hydroxycostal(Organic Chemistry)
- Steroid treatment in patients with membranous nephropathy and hepatitis B virus surface antigenemia : a report of two cases
- Facile Chemical Dehydrogenation of α-Amino Acids Chelated to a Ruthenium(II) Ion:(α-Imino acidato)bis(1, 10-phenanthroline)ruthenium(II) Complexes^
- Syntheses and Characterization of Chloro(Me_2SO)ruthenium(II) Complexes with Tris(2-pyridylmethyl)amine of N, N-Bis(2-pyridylmethyl)glycinate and Their Application for Catalytic Hydroxylation of Alkane
- Synthesis of (±)-Cyclocymopol(Organic Chemistry)
- Kinetic studies on the amination of leucoquinizarin.
- Ullmann condensation reaction of haloanthraquinone derivatives with amines in aprotic solvents.
- The Ullmann condensation reaction of haloanthraquinone derivatives with amines in aprotic solvents. II. The presence of an induction period in the condensation with 2-aminoethanol.
- Asymmetric hydrogenation of .ALPHA.-keto acid derivatives with Rh(I)-chiral diphosphinite system. Effect of halide counterion on the asymmetric induction.
- The Ullmann condensation reaction of haloanthraquinone derivatives with amines in aprotic solvents. VI. The combination of Cu(I) and hydroxo or alkoxo Cu(II) as effective catalyst system.
- Synthesis of Naphth(1,2,3-cd)indol-6(2H)-one Derivatives and Their Fluorescence Properties.
- Synthesis of Azonia Derivatives of Benzoperylene and Benzocoronene by Photocyclization.
- The Ullmann condensation reaction of haloanthraquinone derivatives with amines in aprotic solvents. III. The formation and role of copper(II) species in the condensation with 2-aminoethanol by copper(I) catalyst.
- Amide ion formation and N-alkylation of aminoanthraquinones in the presence of potassium hydroxide in dimethyl sulfoxide.
- Synthesis of 2,6-dihydronaphth(1,2,3-cd)indol-6-ones.
- The Ullmann condensation reaction of haloanthraquinone derivatives with amines in aprotic solvents. V. The formation of active catalyst by the partial oxidation of copper(I) with molecular oxygen.
- The Ullmann condensation reaction of haloanthraquinone derivatives with amines in aprotic solvents. IV. Kinetic studies of the condensation with ethylenediamine.
- Effects of solvent and temperature on the 1,4-asymmetric induction in the diastereoselective hydrogenation of dehydrodipeptides.
- Asymmetric hydrogenation of dehydroamino acids and dehydrodipeptides with rhodium(I)-modified DIOP catalysts.
- The Electrochemical Behavior of the Low-valent Transition Metal Complexes. II. Iron(0)-2,2′-Bipyridine Complexes
- The Electrochemical Behavior of the Low-valent Transititon-metal Complexes. I. Nickel-2,2′-Dipyridyl Complexes.