The Reduction of Aquopentamminechromium(III) Ions at the Dropping Mercury Electrode
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概要
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The reduction of aquopentamminechromium-(III) ions at the dropping mercury electrode has been studied in acid solutions by means of the measurement of the direct current, the alternating current and the Kalousek polarograms and the current-time curves. The d. c. polarogram gives a well-defined wave corresponding to the one-electron reduction of chromium (III) to chromium (II). All polarograms, including the Kalousek ones, indicate the irreversibility of the reduction of aquopentamminechromium(III) ions. The heterogeneous rate constants at 0 V. vs. SCE at various temperatures have been presented, and the possible mechanisms for the electrode process have been discussed.
- 社団法人 日本化学会の論文
著者
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Sato Gen
Department Of Chemistry Faculty Of Science And Technology Sophia University
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TANAKA N.
Department of Health And Physical Education, Kyoto Sangyou University
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Sato Yuichi
Department Of Applied Chemistry Faculty Of Engineering Kanagawa University
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Tamamushi Reita
Department of Chemistry Faculty of Science Tohoku University
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Sato Yuichi
Department of Chemistry Faculty of Science Tohoku University
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