The Kinetics of Substitution Reactions Involving Metal Complexes. IV. Reaction between Lead and Zinc-Ethylenediaminetetraacetate Complexes in Aqueous Solutions
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概要
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The kinetic study of the substitution reaction of lead ions and zinc-EDTA complexs in acetate buffer solutions has been carried out with the same procedure as that reported previously. Under the experimental conditions, the reaction is found to proceed simultaneously through three different reaction paths, and the rate constants for three elementary reactions of those reaction paths are determined at ionic strength 0.2 at 15 and 25°C. The heats of activation and the entropies of activation for the three elementary reactions are calculated.
- 社団法人 日本化学会の論文
著者
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Kato Kiyoko
Department Of Molecular Genetics Division Of Molecular And Cell Therapeutics Medical Institute Of Bi
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TANAKA N.
Department of Health And Physical Education, Kyoto Sangyou University
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Kato Kiyoko
Department of Chemistry Faculty of Science Tohoku University
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