The Formation Constants of Metal Acetate Complexes. III. Polarographic Determination of the Formation Constants of Acetatocadmium(II) and Acetatocobalt(II) Complexes
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概要
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The formation constants of acetatocadmium-(II) and acetatocobalt(II) complexes were determined at ionic strength of 0.2 at 15, 25 and 35°C with the procedure that is based on the polarographic measurement of the sum of the equilibrium concentrations of the hydrated metal ions and the metal acetate complexes in the substitution reaction involving EDTA complexes. The resulting formation constants <I>K</I><SUB>CdOAc</SUB> and <I>K</I><SUB>CoOAc</SUB> are 27 and 2.1 at 15°C, 16 and 0.6 at 25°C and 20 and 0.6 at 35°C, respectively.
- 社団法人 日本化学会の論文
著者
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Sato Gen
Department Of Chemistry Faculty Of Science And Technology Sophia University
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TANAKA N.
Department of Health And Physical Education, Kyoto Sangyou University
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Kamada Minoru
Department of Chemistry Faculty of Science Tohoku University
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Osawa Hisao
Department of Chemistry Faculty of Science Tohoku University
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