不飽和脂肪酸の重合に関する研究 (第3報) : 塩化オキザリルおよびリン化合物の存在下におけるリノール酸メチルの重合反応について

概要

論文の詳細を見る
The polymerization of methyl linoleate in the presence of oxalyl chloride, phosphorus trichloride, phosphorus oxychloride, and phosphoric acid was studied under various reaction conditions. In the case of oxalyl chloride and phosphorus trichloride, the polymers were obtained in high yields and both maximum polymer contents of the crude reaction products were about 66%.<BR>The dimers separated from reaction products with phosphorus trichloride and oxalyl chloride catalysts were analyzed. The results show the presence of six-membered ring structure in the dimers and it is considered that the polymerization reaction with phosphorus trichloride catalyst involves mainly the Diels-Alder reaction.
社団法人日本油化学会の論文