Electrochemical Behavior of a Ferrocene-Modified Cationic Surfactant Mixed with an Anionic Surfactant in Aqueous Solutions
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概要
- 論文の詳細を見る
The aggregation behavior of molecular assemblies formed between oppositely charged surfactants in water was investigated through measurements of the electrochemical behavior of the cationic component, 11-ferrocenylundecyltrimethylammonium bromide (FTMA), in mixtures with the anionic component, sodium dodecylbenzenesulfonate (SDBS). FTMA/SDBS mixture was found to form various types of molecular assemblies such as micelles and vesicles in aqueous solutions depending on the mixing ratio. Cyclic voltammogram on FTMA in the molecular assemblies showed that the peak of oxidation current due to FTMA/SDBS complexes consisting of vesicles is observed on the anodic side of that due to FTMA moleculs consisting of mixed micelles. Moreover, electrochemical measurements on the total surfactant concentration dependence of the phase behavior in solutions of 1:0.4 molar ratio of FTMA and SDBS revealed that vesicles begin to form at a concentration (critical aggregation concentration; cac) much lower than the critical micelle concentration (cmc) of FTMA alone and a phase containing both vesicles and micelles appears at a concentration higher than the cmc.
- 日本油化学会の論文
- 2002-02-01
著者
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ABE Masahiko
Department of Internal Medicine, Hokkaido Prefectural Haboro Hospital
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Sakai Hideki
Department of Pure and Applied Chemistry, Faculty of Science and Technology, Tokyo University of Sci
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Tsuchiya Koji
Dep. Of Pure And Applied Chemistry In Fac. Of Sci. And Technol. And Res. Inst. For Sci. And Technol.
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Abe Masahiko
Fac. Of Sci. And Technol. Tokyo Univ. Of Sci.
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Abe Masahiko
東京理科大学 理工学部
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Tsuchiya Koji
Department Of Cardiovascular Surgery Yamanashi Central Hospital
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Abe Masahiko
Department Of Internal Medicine Hokkaido Prefectural Haboro Hospital
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Abe Masahiko
Faculty Of Science And Technology Tokyo University Of Science
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酒井 秀樹
東京理科大学
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KWON Kyungok
Korea Fire Equipment Inspection Corporation
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TAKEI Takuo
Department of Pure and Applied Chemistry, Tokyo University of Science
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TABOHASHI Tatsuru
Ajinomoto Co., Inc., Amino Science Laboratories
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Takei Takuto
Department Of Pure And Applied Chemistry Tokyo University Of Science
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Tabohashi Tatsuru
Ajinomoto Co. Inc. Amino Science Laboratories
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Sakai Hideki
Department Of Nephro-urology Nagasaki University Graduate School Of Biomedical Sciences
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Abe M
Faculty Of Science And Technology Science University Of Tokyo
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Tsuchiya Koji
Department of Applied Chemistry, Faculty of Science, Tokyo University of Science
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Sakai Hideki
Department of Industrial Chemistry, Tokyo University of Science, 2641 Yamazaki, Noda, Chiba 278-8510, Japan
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