Preparation of Polymers by Admiceller Polymerization Method and Their Carbonization
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概要
- 論文の詳細を見る
Radical polymerization was performed of acrylonitrile solubilized in admicelles of sodium dodecylsulfate (SDS), an anionic surfactant, formed on a mica substrate in aqueous solution. An attempt was then made to prepare thin carbon film by stabilizing the polyacrylonitrile film thus formed as precursor and carbonizing it and the surface structure of the sample was observed with an atomic force microscope (AFM) after each of the treating processes. The sample surface after polymerization consisted of layers, each being a smooth ultrathin film at the nanometer level. The acrylonitrile film shrank to form a granular structure on the mica surface after stabilization and the granules aggregated after carbonization. Contact angle measurements on the sample surfcce that untreated mica substrate has a hydrophilic surface, which turns hydrophobic after polymerization and the surface hydrophobicity increases as the treating process proceeds further to stabilization and carbonization.
- 日本油化学会の論文
- 2001-09-01
著者
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Abe Masahiko
Faculty of Science and Technology, Tokyo University of Science
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Abe Masahiko
Fac. Of Sci. And Technol. Tokyo Univ. Of Sci.
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Abe Masahiko
東京理科大学 理工学部
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Abe Masahiko
Faculty Of Science And Technology Science University Of Tokyo
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Abe Masahiko
Faculty Of Science And Technology Tokyo University Of Science
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OCHIAI Masahiro
Faculty of Science and Technology, Science University of Tokyo
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SAKAI Hideki
Institute of Colloid and Interface Science, Science University of Tokyo
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YAMAGUCHI Aritomo
Institute of Colloid and Interface Science, Science University of Tokyo
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YAMASHITA Takashi
Faculty of Science and Technology, Science University of Tokyo
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SUZUKI Noboru
Faculty of Technology, Utsunomiya University
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AOSHIMA Sadahito
Graduate school of Science, Osaka University
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Orita Masanori
Tokyo Univ. Sci. Tokyo Jpn
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OCHIAI Masahiro
Department of Surgery, Fujita Health University School of Medicine
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酒井 秀樹
東京理科大学
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Yamashita Takashi
Faculty Of Science And Technology Tokyo University Of Science
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Ochiai Masahiro
Faculty Of Science And Technology Tokyo University Of Science
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Yamaguchi A
Department Of Pure And Applied Chemistry Faculty Of Science And Technology Tokyo University Of Scien
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Yamashita T
Faculty Of Science And Technology Tokyo University Of Science
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Yamaguchi Aritomo
Department Of Pure And Applied Chemistry Faculty Of Science And Technology Tokyo University Of Scien
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Aoshima S
Department Of Macromolecular Science Graduate School Of Science Osaka University
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Yamashita Takashi
Faculty Of Agriculture Kyushu University
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Abe M
Faculty Of Science And Technology Science University Of Tokyo
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Suzuki Noboru
Department Of Applied Chemistry Faculty Of Engineering Utsunomiya University
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Suzuki Noboru
Faculty Of Fisheries Hokkaido University
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