Electrochemical Behavior of Ferrocene Solubilized in Surfactant Micelles: Electrostatic Interaction between Ferricinium Ion and Anionic Micelles〔和文〕
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概要
- 論文の詳細を見る
Electrochemical behavior of a redox active probe (ferrocene/ferricinium ion redox couple) solubilized in anionic and cationic micelles was examined by cyclic voltammogram (CV) and the properties of solubilizates in these micelles were investigated. CV for ferrocene solubilized in cationic dodecyltrimethylammonium bromide (DTAB) micelles showed a reversible one-electron reversible redox reaction. In CV for ferrocene solubilized in anionic sodium dodecylsulfate (SDS) micelles, an oxidation current peak (peak 2) was noted at 0.4V vs. SCE in addition to the reversible redox wave (peak 1) similar to that in the DTAB system. The origin of the oxidation current peak (peak 2) of ferrocene solubilized in SDS micelles is discussed in terms of electrostatic interactions between anionic dodecylsulfate and cationic ferricinium ions.
- 日本油化学会の論文
- 2001-12-01
著者
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Sakai Hideki
Faculty of Science and Technology, Tokyo University of Science
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Imamura Hitoshi
Faculty of Science and Technology, Tokyo University of Science
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TSUCHIYA Koji
Faculty of Science and Technology, Tokyo University of Science
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Tsuchiya Koji
Dep. Of Pure And Applied Chemistry In Fac. Of Sci. And Technol. And Res. Inst. For Sci. And Technol.
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Abe Masahiko
Fac. Of Sci. And Technol. Tokyo Univ. Of Sci.
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Abe Masahiko
東京理科大学 理工学部
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Abe Masahiko
Faculty Of Science And Technology Science University Of Tokyo
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KAKIZAWA Yasushi
Faculty of Science and Technology, Science University of Tokyo
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Abe Masahiko
Faculty Of Science And Technology Tokyo University Of Science
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酒井 秀樹
東京理科大学
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KWON Kyungok
Korea Fire Equipment Inspection Corporation
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MATSUMI Tatsuya
Faculty of Science and Technology, Science University of Tokyo
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TAKEI Takuto
Faculty of Science and Technology, Science University of Tokyo
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YAMAGUCHI Aritomo
Faculty of Science and Technology, Science University of Tokyo
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ABE Masahiko
Institute of Colloid and Interface Science
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TABOHASHI Tatsuru
Ajinomoto Co., Inc., Amino Science Laboratories
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Yamaguchi A
Department Of Pure And Applied Chemistry Faculty Of Science And Technology Tokyo University Of Scien
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Takei Takuto
Department Of Pure And Applied Chemistry Tokyo University Of Science
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Tabohashi Tatsuru
Ajinomoto Co. Inc. Amino Science Laboratories
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Kakizawa Yasushi
Faculty Of Science And Technology Science University Of Tokyo
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Yamaguchi Aritomo
Faculty Of Science And Technology Tokyo University Of Science
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Matsumi Tatsuya
Faculty Of Science And Technology Science University Of Tokyo
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Yamaguchi Aritomo
Department Of Pure And Applied Chemistry Faculty Of Science And Technology Tokyo University Of Scien
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Abe M
Faculty Of Science And Technology Science University Of Tokyo
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TSUCHIYA Koji
Faculty of Science and Technology, Science University of Tokyo
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SAKAI Hideki
Faculty of Science and Technology, Science University of Tokyo
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IMAMURA Hitoshi
Faculty of Science and Technology, Science University of Tokyo
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