Thiocarbanilide類に対する過酸化ナトリウムの反応(第2報) : N, N'-Diphenylformamidine類の生成について
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概要
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Oxidation of thiocarbanilide (Ia) with sodium peroxide in aqueous ethanol was investigated at room temperature in connection with the previous work in which the same reaction was carried out in boiling water bath to afford carbanilide (IIa) and 1-phenyl-2-benzimidazolinone (IIIa), and N, N'-diphenylformamidine (IVa) was obtained in addition to IIa and (IIIa). In the same manner, starting from 4,4'-diethoxythiocarbanilide (Ib), N, N'-bis (p-ethoxyphenyl) formamidine (IVb) was obtained, together with 4,4'-diethoxycarbanilide (IIb) and 1-(p-ethoxyphenyl)-6-ethoxy-2-benzimidazolinone (IIIb).
- 公益社団法人日本薬学会の論文
- 1968-05-25
著者
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柴崎 寿一郎
Faculty Of Pharmaceutical Sciences Nagasaki University
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小泉 保
Faculty of Pharmaceutical Sciences, Toyama Medical and Pharmaceutical University
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柴崎 寿一郎
長崎大学薬学部
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松村 祐子
長崎大学薬学部
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小泉 保
Faculty Of Pharmaceutical Sciences Toyama Medical And Pharmaceutical University
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小泉 保
長崎大学薬学部
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柴崎 寿一郎
Faculty of Pharmaceutical Sciences, Nagasaki University
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