Glucuronosideの加水分解に関する研究(第4報) : Glucofuranosidurono-3,6-lactoneとGlucopyranosiduronic Acidおよびそれらのα-, β-Anomerの酸およびアルカリによる加水分解
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Rate of acid and alkaline hydrolyses of glucofuranosiduronic acid 3,6-lactone and glucopyranosiduronic acid, and their α- and β-anomers was examined. The 3,6-lactone was hydrolyzed much faster than the acid by either acid or alkali, and the β-anomer of the acid was more rapidly hydrolyzed than the α-anomer. The fairly large minus value of the entropy of activation in the acid-catalyzed hydrolysis of the 3,6-lactone suggested this to be an A-2 reaction. Comparative considerations were made on the kinetic data of glucuronoside and glucoside.
- 公益社団法人日本薬学会の論文
- 1967-05-25
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