Studies on the Racemization of Amino Acids and Their Derivatives. III. The Effect of Alkyl-, Aralkyl- and Aryl-Side Chain at α-Position of Amino Acids on Their Base-Catalyzed Racemization
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概要
- 論文の詳細を見る
Kinetical study was carried out in the base-catalyzed racemization reaction of N-benzoyl anilide derivatives of six neutral amino acids, such as alanine, α-aminobutyric acid, valine, leucine, phenylalanine and phenylglycine. From the comparison of rate-constants thus obtained, it was concluded that the susceptibility of amino acids tested to the racemization may be expressed in thrm of acidity of α-proton related to the electronnegativity of alkyl-, aralkyl- and aryl-side chains at α-carbon.
- 社団法人日本薬学会の論文
- 1970-09-25
著者
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松尾 寿之
Faculty Of Pharmaceutical Sciences University Of Tokyo
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辰野 高司
The Institute of Physical Chemical Research
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松尾 寿之
The Institute of Physical Chemical Research
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佐藤 要
The Institute of Physical and Chemical Research
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辰野 高司
理化学研究所
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辰野 高司
Institute of Physical and Chemical Research
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辰野 高司
The Institute Of Physical And Chemical Research
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