Studies on Aminobutenolide Compounds. I. The Reaction of o-Phthalaldehydic Acid with Amino Compounds
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概要
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An investigation was made on the reaction between o-phthalaldehydic acid (II) and various primary amino compounds. The reaction with aromatic amines afforded 3-arylaminophthalides (IIIa-j) in good yield. However, the reaction with aliphatic amines did not afford expected III type compounds, but 3,3'-(N-alkylimino) diphthalides (VIa-d). Similar type compounds (XIa-e) were prepared from ureas, acetamide, and ethyl carbamate. 3-Chlorophthalide (V) reacted with aniline to afford IIIa, but with aliphatic amines, 3-hydroxy-N-alkylphthalimidines (IXa-d).
- 社団法人日本薬学会の論文
- 1971-06-25
著者
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辰野 高司
The Institute of Physical Chemical Research
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辰野 高司
理研
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辰野 高司
The Institute Of Physical And Chemical Research
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窪田 幸夫
理研
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窪田 幸夫
The Institute of Physical and Chemical Research
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