A NEW STEREOSELECTIVE ROUTE TO γ-BUTYROLACTONES : ASYMMETRIC SYNTHESES OF (+)-trans-WHISKY AND (+)-trans-COGNAC LACTONES
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概要
- 論文の詳細を見る
A new stereoselective route to γ-butyrolactones such as (+)-trans-whisky and (+)-trans-cognac lactones (1a, b) has been developed by a combination of three key reactions : diastereoselective nucleophilic addition of thiophenol, cleavage of chiral N-acylsultam via thioester, and intramolecular displacement of the sulfonium group with carboxylate anion.
- 公益社団法人日本薬学会の論文
- 1992-09-25
著者
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伊達 忠正
Research Laboratories, Tanabe Seiyaku Co., Ltd.
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内藤 猛章
Kobe Women's College of Pharmacy
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宮田 興子
Kobe Women's College of Pharmacy
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岡村 公生
Organic Chemistry Research Laboratory Tanabe Seiyaku Co. Ltd.
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二宮 一彌
Kobe Women's College of Pharmacy
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伊達 忠正
Organic Chemistry Research Laboratory Tanabe Seiyaku Co. Ltd.
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品田 哲郎
Kobe Women's College Of Pharmacy
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内藤 猛章
神戸女子薬科大学
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二宮 一彌
神戸女薬大
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川上 菜奈子
Kobe Women's College of Pharmacy
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田路 恭子
Kobe Women's College of Pharmacy
-
岡村 公生
Research Laboratory, Tanabe Seiyaku, Co., Ltd.,
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二宮 一弥
神戸薬大
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二宮 一彌
Kobe Women's College Of Pharmacy
-
田路 恭子
Kobe Women's College Of Pharmacy
-
川上 菜奈子
Kobe Women's College Of Pharmacy
-
内藤 猛章
神戸薬科大学
-
宮田 興子
神戸薬科大学
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