A New Combined Oxidizing Reagent System, Fe (CH_3CN)^<3+>_6-IO^-_4 : Oxidation of Paraffin Hydrocarbons
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概要
- 論文の詳細を見る
Combined oxidizing reagent systems of Fe (AN)_6 (ClO_4)_3 (AN=acetonitrile) with halogen oxyacids were investigated. In particular, reactions of paraffin hydrocarbons with a combined reagent system of Fe (AN)^<3+>_6-IO^-_4 were explored because of the high reactivity of this system in the oxidation of adamantane (Table I). Oxidations of bornane, norbornane, cyclohexane, and n-hexane gave the corresponding acetamides and acetates (Table II). These results show that the title reagent system can efficiently oxidize organic substrates which have onset potentials of anodic current of ca. 2.7V vs. saturated calomel electrode.
- 社団法人日本薬学会の論文
- 1985-11-25
著者
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小林 茂樹
昭和薬大
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飛永 精照
Showa College of Pharmaceutical Sciences
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小谷 栄一
Showa College of Pharmaceutical Sciences
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小林 茂樹
Showa College of Pharmaceutical Science
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石井 耀子
Showa College of Pharmaceutical Science
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小谷 榮一
Showa College of Pharmaceutical Sciences
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小谷 榮一
昭和薬科大学
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飛永 精照
昭和薬科大学
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Ishi Y
Showa College Of Pharmaceutical Science
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小林 茂樹
Showa College Of Pharmaceutical Sciences
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小谷 栄一
昭和薬科大学
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