Oxygenation of Aromatic and Aliphatic Hydrocarbons by a New Reagent System, Fe (CH_3CN)^<2+>_6-H_2O_2-Ac_2O : An Effective Model Reagent for Mono-oxygenase
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概要
- 論文の詳細を見る
Reactions of aromatic and aliphatic hydrocarbons with a new reagent system, Fe (CH_3CN)^<2+>_6-H_2O_2-Ac_2O in CH_3CN, gave oxygenation products with fairly high reaction efficiency (Tables I and II) compared to known reagent systems used as enzyme models for mono-oxygenases. Investigations of the mechanism of these reactions indicated the involvement of either complex C, Fe^<IV> (OH) (OAc)^<2+>, or complex D, Fe^<IV> (OAc)^<2+>_2,depending on the organic substrate.
- 社団法人日本薬学会の論文
- 1985-11-25
著者
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小林 茂樹
昭和薬大
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飛永 精照
Showa College of Pharmaceutical Sciences
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小谷 栄一
Showa College of Pharmaceutical Sciences
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小林 茂樹
Showa College of Pharmaceutical Science
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石井 耀子
Showa College of Pharmaceutical Science
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小谷 榮一
Showa College of Pharmaceutical Sciences
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小谷 榮一
昭和薬科大学
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飛永 精照
昭和薬科大学
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Ishi Y
Showa College Of Pharmaceutical Science
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小林 茂樹
Showa College Of Pharmaceutical Sciences
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小谷 栄一
昭和薬科大学
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