Preparation and Reactivities of Hexakisacetonitrile Iron (III) Perchlorate and Related Complexes as Strong Oxidizing Reagents

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概要

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• The iron (III) complexes Fe (S)_6(ClO_4)_3,S=solvent, were prepared from Fe (H_2O)_6(ClO_4)_3 in the donor solvents. Reactions of alkylbenzenes with Fe(AN)_6(ClO_4)_3 (AN=acetonitrile) were explored because the AN complex has the highest formal redox potential, E°=1.73 V vs. SCE, among these complexes. Oxidation of the primary alkylbenzenes by the iron (III) AN complex gave the corresponding acetamides (Table II). Oxidation of the secondary alkylbenzenes, namely, cumene, 2-phenylbutane, and 2-exo-phenylnorborane, afforded the corresponding acetates and acetamides (Charts 2 and 3), consuming over 4 mol eq of reagent. Reactions of p-xylene and hexamethylbenzene with Fe (CH_2=CHCN)_6(ClO_4)_3 also yielded the amides 31a and 31b. These results demonstrate the applicability of the iron (III) AN complex as a powerful reagent to oxidize organic substrates which have onset potentials of anodic current of ca. 2.0 V vs. SCE.

• 社団法人日本薬学会の論文
• 1984-11-25

著者

• 小林 茂樹

  昭和薬大

• 小谷 栄一

  Showa College of Pharmaceutical Sciences

• 小林 茂樹

  Showa College of Pharmaceutical Science

• 石井 耀子

  Showa College of Pharmaceutical Science

• 小谷 榮一

  Showa College of Pharmaceutical Sciences

• 小谷 榮一

  昭和薬科大学

• 飛永 精照

  昭和薬科大学

• Ishi Y

  Showa College Of Pharmaceutical Science

• 小林 茂樹

  Showa College Of Pharmaceutical Sciences

• 小谷 栄一

  昭和薬科大学

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