The Aconite Alkaloids. XXIII. The Structure of Ignavine. (3).

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概要

• 論文の詳細を見る

• The presence of α-methylenecyclohexanol grouping in ignavine or des-N-methyl-anhydroignavinol was proved by rearrangement reaction to ketone. Oxidative cleavage of the cyclohexanol ring in des-N-methylanhydroignavinol gave a dicarboxylic and one of the carboxyl groups in this acid was confirmed as tertiary. α-Glycol group which is another functional group in des-N-methylanhydroignavinol was also cleaved by oxidation to give a dicarboxylic acid and the glycol was proved to exist at carbons γ ond δ to the nitrogen.

• 公益社団法人日本薬学会の論文
• 1959-07-20

著者

• 岡本 敏彦

  Faculty of Pharmaceutical Sciences, University of Tokyo

• 岡本 敏彦

  Faculty Of Pharmaceutical Sciences University Of Tokyo

• 岡本 敏彦

  Sato Pharmaceutical Co. Ltd.

• 落合 英二

  Faculty of Pharmaceutical Sciences, University of Tokyo

• 落合 英二

  Pharmazeutische Fakultat Universitat Tokyo

• 落合 英二

  Faculty Of Pharmaceutical Sciences University Of Tokyo And Research Laboratory Shionogi & Co. Lt

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