Catalytic Reduction of Heterocyclic Aromatic Amine Oxides with Raney Nickel. II. Reduction of 4-Substituted Quinoline 1-Oxide Derivatives.

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概要

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• Quinoline 1-oxide and various 4-substituted quinoline 1-oxide derivatives were submitted to catalytic reduction over Raney nickel as a catalyst and results obtained were similar to the case of pyridine derivatives described in the preceding paper. In all cases, compounds were reduced smoothly and in a good yield. In the case of 4-benzyloxyquinoline 1-oxide, the first mole of hydrogen is absorbed rapidly while the next mole of hydrogen is absorbed very slowly, and 4-benzyloxyquinoline 1-oxide is reduced to (X) via 4-benzyloxyquinoline (XIII). This is somewhat different from the behavior of 4-benzyloxypyridine 1-oxide to catalytic reduction over Raney nickel.

• 公益社団法人日本薬学会の論文
• 1959-03-20

著者

• 清水 和子

  Shizuoka College Of Pharmacy

• 林 英作

  Shizuoka College of Pharmacy

• 山中 宏

  Shizuoka College of Pharmacy

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