Catalytic Reduction of 4-Benzyloxy-6-methylpyrimidine and Related Compounds.
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概要
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Catalytic reduction of 4-benzyloxy-6-methylpyrimidine 1-oxide in methanol over palladium-carbon resulted in the formation of 6-methyl-4-pyrimidinol via 4-hydroxy-6-methylpyrimidine 1-oxide. The use of Raney nickel as a catalyst in this case afforded 4-benzyloxy-6-methylpyrimidine and this is a new type of reaction not recorded in past literature.
- 公益社団法人日本薬学会の論文
- 1959-03-20
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関連論文
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- A New Deoxygenation Reaction of an Aromatic Heterocyclic N-Oxides
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- On the Reaction of 4-Phenoxy-6-methylpyrimidine 1-Oxide with Nucleophilic Reagents.
- Studies on the Synthesis of 4-Methoxypyrimidine 1-Oxide and its Reissert Reaction.
- Catalytic Reduction of 4-Benzyloxy-6-methylpyrimidine and Related Compounds.
- Reaction of 4-Alkoxyquinazolines with Organic Peracid.
- Catalytic Reduction of Heterocyclic Aromatic Amine Oxides with Raney Nickel. III. Reduction of Hydroxamic Acid-type N-Oxides.
- On the Reactivity of 2,6-Dimethyl-pyrimidine-4-carbonitrile.
- Studies on 4-Alkoxy-6-methyl-pyrimidine N-Oxides.