Aminodienylesters. I : The Cycloaddition Reactions of tert-Aminodienylester with α, β-Unsaturated Carbonyl Compounds, Styrenes, and Quinones
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概要
- 論文の詳細を見る
Methyl 5-(N, N-dimethylamino)-2,4-pentadienoate (tert-aminodienylester 1) was synthesized by condensation of methyl crotonate (2) with N, N, N', N'-tetramethylmethylenediamine (3). The reactivity of 1 was investigated with methyl propiolate (4), dimethyl 2-butynedionate (5), dimethyl maleae (6), dimethyl fumarate (7), 2-buten-4-olide (8), 2-cyclohexenone (9), styrene (10), trans-β-nitrostyrene (11), 1,4-benzoquinone (19), methyl 1,4-naphtoquinone-5-carboxylate (21), 1,4-naphthoquinone (24), juglone (26), 5-methoxy-1,4-naphthoquinone (28), naphthazarin (31), and naphthazarin dimethyl ether (33). In addition, 5-(N, N-dimethylamino)-2,4-pentadienenitrile (tert-aminodienylnitrile 37) was synthesized by condensation of crotononitrile (36) with 3. The reactivity of 37 was investigated with dimethyl 2-butynedionate (5), and 2-cyclohexenone (9).
- 公益社団法人日本薬学会の論文
- 1997-02-15
著者
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Takeuchi Naoki
Showa Pharmaceutical University
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Takeuchi Naoki
Showa College Of Pharmaceutical Sciences
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Koike Tohru
Dep. Of Functional Molecular Sci. Graduate School Of Biomedical Sciences Hiroshima Univ. Kasumi 1-2-
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Takeuchi N
Showa Pharmaceutical University
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TOBINAGA Seisho
Showa College of Pharmaceutical Sciences
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KOIKE Takeshi
Showa Pharmaceutical University
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TANABE Mituharu
Showa College of Pharmaceutical Sciences
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Tanabe M
Osaka University Of Pharmaceutical Sciences
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Takeuchi N
Meijo Univ. Nagoya Jpn
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Tanabe M
Showa College Of Pharmaceutical Sciences
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Tobinaga S
Showa Pharmaceutical University
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