ペロブスカイト構造を有する等方性多結晶La-AM-Mn-O(AM=K, Rb)セラミックスの巨大磁気抵抗効果

概要

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Polycrystalline isotropic perovskite-like La-AM-Mn-O compounds(AM=K, Rb)with trivalent La_<3+> partially substituted for pseudo-divalent cations(a half of trivalent La_<3+> plus a half of monovalent K^+ or Rb^+)were fabricated by conventional ceramic techniques, and their magnetoresistance effects and magnetic/electric properties were studied. All studied samples show ferromagnetism and high electrical conductivity at low temperature of 77 K. As sintering temperature increases, Curie temperature, saturation magnetization and resistivity decrease. Polycrystalline isotropic La-K-Mn-O sample shows a large negative magnetoresistance effect of -25% at H=1.5 T and T=280 K. This value is comparable to the value previously reported in La_<1-x>Me_xMnO_3(Me=divalent cation)single crystal.
社団法人日本セラミックス協会の論文
1996-02-01