高圧力技術を利用した水素貯蔵材料の合成と探索

概要

論文の詳細を見る
Among metal hydrides, magnesium hydride (MgH2) would be a promising candidate for hydrogen storage materials because of its high hydrogen-storage capacity (7.6 mass%). However, the dehydrogenation temperature is too high for wide practical applications. Novel magnesium-based hydrides with better dehydrogenation properties than MgH2 can be prepared under hydrogen pressure of gigapascal (GPa). For instance, Mg7TiH16 (6.9 mass%) would release hydrogen at a lower temperature by 130 K than MgH2. The Mg-H ionic bonding distance in Mg7TiH16 is longer than that in MgH2. The observed lower dehydrogenation temperature seems to be consistent with the structure.
日本高圧力学会の論文
2007-08-20