High-Pressure Raman Study of Carbon Tetrafluoride up to 8 GPa
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概要
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High-pressure Raman spectra of carbon tetrafluoride (CF.) have been measured upto 8 GPa at 300 K in a gasketed diamond anvil cell. The pressure dependence of fourintramolecular vibrations has been investigated. The liquid-solid I, solid I-II andsolid II-III phase transitions at respective pressures 1.86 GPa, 2.84 GPa and 3.5 GPaare presented by the splitting of vibrational modes and the drastic change in Ramanband widths. The observed solid I and II phases correspond to plastic (non-cubic) andmonoclinic phases, respectively, that also appear at low temperatures and atmospheric pressure. The solid III phase above 3.5 GPa is a new phase. These transi-tion pressures are supported by the good agreement with those obtained by extrapola-lion (to 300 K) of phase boundaries previously determined at low temperatures.[carbon tetrafluoride, plastic phase, high-pressure, diamond anvil cell, Raman l[ scattering, phase transitionl
- 社団法人日本物理学会の論文
- 1991-05-15
著者
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Shimizu Hiroyasu
Department Of Electrical Engineering Faculty Of Engineering Gifu University:the Institute Of Optics
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Shimizu Hiroyasu
Department Of Electronics And Computer Engineering Faculty Of Engineering Gifu University
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Ikeda Yukio
Department Of Earth Sciences Faculty Of Science Ibaraki University
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Sasaki Shigeo
Department Of Chemistry Faculty Of Science Kyushu University
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Sasaki Shigeo
Department Of Electronics And Computer Engineering Faculty Of Engineering Gifu University
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Ikeda Yukio
Department Of Electronics And Computer Engineering Faculty Of Engineering Gifu University
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Ikeda Yukio
Department Of Earth Science Faculty Of Science Ibaraki University
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