Pressure-Induced Phase Transition in Crystalline DCOOD by Raman Scattering in the Diamond Cell
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概要
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The Raman spectra of crystalline deuterated formic acid (DCOOD) in adiamond anvil cell have been measured at pressures up to 100 kbar and 300 K.The frequency of the stretching 0 -D mode near 2000 cm ' decreases stronglywith increasing pressure, which is due to the increasing strength of the deuteriumbonds in the zig-zag chain. The pressure-induced phase transition at about45 kbar has been found on the characteristic high-pressure behavior of thestretching O-D, the stretching C=0, and the bending C-D modes, which isdiscussed by focusing on the cis-trans conformational change associated with thedeuteron transfer.
- 社団法人日本物理学会の論文
- 1985-08-15
著者
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Shimizu Hiroyasu
Department Of Electrical Engineering Faculty Of Engineering Gifu University:the Institute Of Optics
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Ikuta Fujiya
Department Of Electrical Engineering Gifu University:hitachi Chubu Soltware Ltd. Haruoka
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