Strontium Isotope Effect in Liquid-Liquid Extraction of Strontium Chloride Using a Crown Ether
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概要
- 論文の詳細を見る
Isotope effects in a liquid-liquid extraction of strontium with dicyclohexano-18-crown-6 (DC18C6) were investigated. Unit mass enrichment factors were observed to increase with concentrations of strontium salt in an aqueous phase. Isotope distinguishing ability of DC18C6 to strontium isotopes was calculated as an intrinsic separation factor to be K<SUB>c</SUB>=1.00051±0.00004. An odd mass number isotope, <SUP>87</SUP>Sr, was recognized to behave differently from even mass number isotopes, <SUP>84</SUP>Sr, <SUP>86</SUP>Sr and <SUP>88</SUP>Sr. The enrichment factor induced by a nuclear property (odd or even mass number) other than the mass difference was ε<SUB>O/E</SUB>=-8.0×10<SUP>-4</SUP> which was observed with 3.2M Sr aqueous solution. Isotope shift of energy state for 5s-orbital of strontium produces the isotope shift in vibrational energy between the strontium ion and the DC18C6.
- 社団法人 日本原子力学会の論文
- 1995-12-25
著者
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Yamamoto Tadashi
Department of Structural Pathology Institute of Nephrology, Graduate School of Medical and Dental Sc
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Yamamoto Tadashi
Department Of Cardiology Kouseikai Hospital
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Yamamoto T
Mitsubishi Electric Corp.
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HOSOE Morikazu
Department of Earth and Ocean Science, The National Defense Academy
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NISHIZAWA Kazushige
Department of Nuclear Engineering, Graduate School of Osaka University
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MIKI Takahito
Department of Nuclear Engineering, Graduate School of Osaka University
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SATOYAMA Tomonori
Department of Nuclear Engineering, Osaka University
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Miki Takahito
Department Of Nuclear Engineering Osaka University
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Nishizawa Kazushige
Department Of Nuclear Engineering Osaka University
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Nishizawa Kazushige
Department Of Nuclear Engineering Graduate School Of Engineering Osaka University
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Satoyama Tomonori
Department Of Nuclear Engineering Osaka University
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Yamamoto Takao
Department Of Nuclear Engineering Osaka University
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Yamamoto Tadashi
Departmanets of Structural Pathology, Institute of Nephrology, Graduate School of Medical and Dental Sciences, Niigata University
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